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Selective non-catalytic reduction (SNCR) is a method to lessen nitrogen oxide emissions in conventional power plants that burn biomass, waste and coal.The process involves injecting either ammonia or urea into the firebox of the boiler at a location where the flue gas is between 1,400 and 2,000 °F (760 and 1,090 °C) to react with the nitrogen oxides formed in the combustion process.
In the Bowin burner, air and fuel gas are premixed at a ratio greater than or equal to the stoichiometric combustion requirement. [39] Water Injection technology, whereby water is introduced into the combustion chamber, is also becoming an important means of NO x reduction through increased efficiency in the overall combustion process ...
This is sometimes called the reverse water–gas shift reaction. [20] Water gas is defined as a fuel gas consisting mainly of carbon monoxide (CO) and hydrogen (H 2). The term 'shift' in water–gas shift means changing the water gas composition (CO:H 2) ratio. The ratio can be increased by adding CO 2 or reduced by adding steam to the reactor.
To achieve a reduction from 25 ppm to 9 ppm more than 6 percent air must pass through the premixer. [5] Newer generations of DLE burners have an extra injection leading to better control. [5] Additional systems like "selective catalytic reduction" (SCR) are necessary to achieve emissions lower than 2.5 ppm. [5]
2), and water (H 2 O). A reductant, typically anhydrous ammonia (NH 3), aqueous ammonia (NH 4 OH), or a urea (CO(NH 2) 2) solution, is added to a stream of flue or exhaust gas and is reacted onto a catalyst. As the reaction drives toward completion, nitrogen (N 2), and carbon dioxide (CO 2), in the case of urea use, are produced. Selective ...
The vapor pressure of the water in the gas mixture produced during catalyst formation is thus kept as low as possible, target values are below 3 gm −3. For this reason, the reduction is carried out at high gas exchange, low pressure, and low temperatures. The exothermic nature of the ammonia formation ensures a gradual increase in temperature ...
Paul Sabatier (1854-1941) winner of the Nobel Prize in Chemistry in 1912 and discoverer of the reaction in 1897. The Sabatier reaction or Sabatier process produces methane and water from a reaction of hydrogen with carbon dioxide at elevated temperatures (optimally 300–400 °C) and pressures (perhaps 3 MPa [1]) in the presence of a nickel catalyst.
A methane reformer is a device based on steam reforming, autothermal reforming or partial oxidation and is a type of chemical synthesis which can produce pure hydrogen gas from methane using a catalyst. There are multiple types of reformers in development but the most common in industry are autothermal reforming (ATR) and steam methane ...