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HBr can be prepared by distillation of a solution of sodium bromide or potassium bromide with phosphoric acid or sulfuric acid: [14] KBr + H 2 SO 4 → KHSO 4 + HBr. Concentrated sulfuric acid is less effective because it oxidizes HBr to bromine: 2 HBr + H 2 SO 4 → Br 2 + SO 2 + 2 H 2 O. The acid may be prepared by: reaction of bromine with ...
The radical groups can then interact with HBr to produce a Br radical, which then reacts with the double bond. Since the bromine atom is relatively large, it is more likely to encounter and react with the least substituted carbon since this interaction produces less static interactions between the carbon and the bromine radical.
In organic chemistry, free-radical halogenation is a type of halogenation. This chemical reaction is typical of alkanes and alkyl-substituted aromatics under application of UV light. The reaction is used for the industrial synthesis of chloroform (CHCl 3), dichloromethane (CH 2 Cl 2), and hexachlorobutadiene. It proceeds by a free-radical chain ...
Hypobromous acid has a pK a of 8.65 and is therefore only partially dissociated in water at pH 7. Like the acid, hypobromite salts are unstable and undergo a slow disproportionation reaction to yield the respective bromate and bromide salts. 3 BrO − (aq) → 2 Br − (aq) + BrO − 3 (aq)
A redox reaction of hypobromous acid (HBrO) can form bromous acid (HBrO 2) as its product: [citation needed] HBrO + H 2 O − 2e − → HBrO 2 + 2H + The disproportionation reaction of two equivalents hypobromous acid (HBrO) results in the formation of both bromous acid (HBrO 2) and hydrobromic acid (HBr): [citation needed] 2 HBrO → HBrO 2 + HBr
This reaction occurs in a similar way to the addition reaction but has an extra step in which the OSO 3 H group is replaced by an OH group, forming an alcohol: C 2 H 4 + H 2 O → C 2 H 5 OH. As can be seen, the H 2 SO 4 does take part in the overall reaction, however it remains unchanged so is classified as a catalyst. This is the reaction in ...
A hydrohalogenation reaction is the electrophilic addition of hydrogen halides like hydrogen chloride or hydrogen bromide to alkenes to yield the corresponding haloalkanes. [ 1 ] [ 2 ] [ 3 ] If the two carbon atoms at the double bond are linked to a different number of hydrogen atoms, the halogen is found preferentially at the carbon with fewer ...
Hydrobromic acid is an aqueous solution of hydrogen bromide.It is a strong acid formed by dissolving the diatomic molecule hydrogen bromide (HBr) in water. "Constant boiling" hydrobromic acid is an aqueous solution that distills at 124.3 °C (255.7 °F) and contains 47.6% HBr by mass, which is 8.77 mol/L. Hydrobromic acid is one of the strongest mineral acids known.