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The basic hydroxo complex [Pb 6 O(OH) 6] 4+ is a cluster of six lead centres with metal–metal bonds surrounding a central oxide ion. The six hydroxide groups lie on the faces of the two external Pb 4 tetrahedra. In strongly alkaline solutions soluble plumbate ions are formed, including [Pb(OH) 6] 2−. [28]
In chemistry, metal hydroxides are a family of compounds of the form M n+ (OH) n, where M is a metal. They consist of hydroxide ( OH − ) anions and metallic cations , [ 1 ] and are often strong bases .
Iron(II) sulfate – FeSO 4; Iron(III) chloride – FeCl 3; Iron(III) fluoride – FeF 3; Iron(III) oxalate – C 6 Fe 2 O 12; Iron(III) oxide – Fe 2 O 3; Iron(III) nitrate – Fe(NO 3) 3 (H 2 O) 9; Iron(III) sulfate – Fe 2 (SO 4) 3; Iron(III) thiocyanate – Fe(SCN) 3; Iron(II,III) oxide – Fe 3 O 4; Iron ferrocyanide – Fe 7 (CN) 18 ...
Therefore, the name of the metal or positive polyatomic ion is followed by the name of the non-metal or negative polyatomic ion. The positive ion retains its element name whereas for a single non-metal anion the ending is changed to -ide. Example: sodium chloride, potassium oxide, or calcium carbonate.
Iron(III) oxide is a product of the oxidation of iron. It can be prepared in the laboratory by electrolyzing a solution of sodium bicarbonate, an inert electrolyte, with an iron anode: 4 Fe + 3 O 2 + 2 H 2 O → 4 FeO(OH) The resulting hydrated iron(III) oxide, written here as FeO(OH), dehydrates around 200 °C. [18] [19] 2 FeO(OH) → Fe 2 O 3 ...
Green vitriol is iron(II) sulfate heptahydrate, FeSO 4 ·7H 2 O; blue vitriol is copper(II) sulfate pentahydrate, CuSO 4 ·5H 2 O and white vitriol is zinc sulfate heptahydrate, ZnSO 4 ·7H 2 O. Alum , a double sulfate of potassium and aluminium with the formula K 2 Al 2 (SO 4 ) 4 ·24H 2 O , figured in the development of the chemical industry.
Potassium ferrioxalate contains the iron(III) complex [Fe(C 2 O 4) 3] 3−. In chemistry, iron(III) or ferric refers to the element iron in its +3 oxidation state. Ferric chloride is an alternative name for iron(III) chloride (FeCl 3). The adjective ferrous is used instead for iron(II) salts, containing the cation Fe 2+.
The iron compounds produced on the largest scale in industry are iron(II) sulfate (FeSO 4 ·7H 2 O) and iron(III) chloride (FeCl 3). The former is one of the most readily available sources of iron(II), but is less stable to aerial oxidation than Mohr's salt ( (NH 4 ) 2 Fe(SO 4 ) 2 ·6H 2 O ).