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Typically coal liquefaction processes are associated with significant CO 2 emissions from the gasification process or as well as from generation of necessary process heat and electricity inputs to the liquefaction reactors, [10] thus releasing greenhouse gases that can contribute to anthropogenic global warming.
In industrial chemistry, coal gasification is the process of producing syngas ... in "BTU Conversion" technologies such as gasification, methanation and liquefaction.
The chemical composition of syngas varies based on the raw materials and the processes. Syngas produced by coal gasification generally is a mixture of 30 to 60% carbon monoxide, 25 to 30% hydrogen, 5 to 15% carbon dioxide, and 0 to 5% methane. It also contains lesser amount of other gases. [10]
The Fischer–Tropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons. [1] In the usual implementation, carbon monoxide and hydrogen, the feedstocks for FT, are produced from coal, natural gas, or biomass in a process known as gasification.
As an example of the latter, a "major commercial application of liquefaction is the liquefaction of air to allow separation of the constituents, such as oxygen, nitrogen, and the noble gases." [4] Another is the conversion of solid coal into a liquid form usable as a substitute for liquid fuels. [5]
Coal gasification is a process whereby a hydrocarbon feedstock (coal) is converted into gaseous components by applying heat under pressure in the presence of steam. Rather than burning, most of the carbon-containing feedstock is broken apart by chemical reactions that produce "syngas."
In many ways, Germany took the lead in coal gas research and carbon chemistry. With the labours of August Wilhelm von Hofmann, the whole German chemical industry emerged. Using the coal gas waste as feedstock, researchers developed new processes and synthesized natural organic compounds such as Vitamin C and aspirin.
Coal liquefaction emits more carbon dioxide than liquid fuel production from crude oil. Mixing in biomass and using carbon capture and storage (CCS) would emit slightly less than the oil process but at a high cost. [101] State owned China Energy Investment runs a coal liquefaction plant and plans to build 2 more. [102]