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The distribution coefficient, log D, is the ratio of the sum of the concentrations of all forms of the compound (ionized plus un-ionized) in each of the two phases, one essentially always aqueous; as such, it depends on the pH of the aqueous phase, and log D = log P for non-ionizable compounds at any pH.
If different species occur in the octanol-water system by dissociation or association, several P-values and one D-value exist for the system. If, on the other hand, the substance is only present in a single species, the P and D values are identical. P is usually expressed as a common logarithm, i.e. Log P (also Log P ow or, less frequently, Log ...
Milton Abramowitz and Irene A. Stegun, Handbook of Mathematical Functions with Formulas, Graphs, and Mathematical Tables, 1964. A few integrals are listed on page 69 . v
Logarithms can be used to make calculations easier. For example, two numbers can be multiplied just by using a logarithm table and adding. These are often known as logarithmic properties, which are documented in the table below. [2] The first three operations below assume that x = b c and/or y = b d, so that log b (x) = c and log b (y) = d.
Most computerized databases will create a table of thermodynamic values using the values from the datafile. For MgCl 2 (c,l,g) at 1 atm pressure: Thermodynamic properties table for MgCl 2 (c,l,g), from the FREED datafile. Some values have truncated significant figures for display purposes. The table format is a common way to display ...
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The chemical model will include values of the protonation constants of the ligand, which will have been determined in separate experiments, a value for log K w and estimates of the unknown stability constants of the complexes formed. These estimates are necessary because the calculation uses a non-linear least-squares algorithm. The estimates ...
Schedule K is a geographic coding scheme originally developed by the United States Maritime Administration and currently maintained by the United States Army Corps of Engineers to identify seaports handling waterborne shipments involved with foreign trade of the United States.