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2-Naphthalenethiol is prepared from 2-naphthol by the Newman–Kwart rearrangement starting from a thiocarbamate. [1] It undergoes lithiation at the 1 and 3-position. [2] [3] It can be used as a flavouring agent and has been described as having an “artichoke”, “meaty” and “creamy” taste”. [4] [5]
Traditionally, 2-naphthol is produced by a two-step process that begins with the sulfonation of naphthalene in sulfuric acid: [2] C 10 H 8 + H 2 SO 4 → C 10 H 7 SO 3 H + H 2 O. The sulfonic acid group is then cleaved in molten sodium hydroxide: C 10 H 7 (SO 3 H) + 3 NaOH → C 10 H 7 ONa + Na 2 SO 3 + 2 H 2 O. Neutralization of the product ...
The UOP characterisation factor (K w) (UOP 375-07 [2]), is based on the observation that the specific gravities of the hydrocarbons are related to their H/C ratio (and thus to their chemical character) and that their boiling points are linked to their number of carbon atoms in their molecules. High values of Kw (13-12.5) indicate a ...
[1] 1-Naphthalenethiol can also be prepared from 1-bromonaphthalene by Pd-catalyzed reaction with the silylthiolate i Pr 3 SiSK followed by hydrolysis of the silathioether. [2] It was first prepared from the Grignard reagent generated from 1-bromonaphthalene. Treatment of that reagent with elemental sulfur followed by acidification gave the ...
Petroleum naphtha is an intermediate hydrocarbon liquid stream derived from the refining of crude oil [1] [2] [3] with CAS-no 64742-48-9. [4] It is most usually desulfurized and then catalytically reformed, which rearranges or restructures the hydrocarbon molecules in the naphtha as well as breaking some of the molecules into smaller molecules to produce a high-octane component of gasoline (or ...
Naphtha (/ ˈ n æ f θ ə /, recorded as less common or nonstandard [1] in all dictionaries: / ˈ n æ p θ ə /) is a flammable liquid hydrocarbon mixture.Generally, it is a fraction of crude oil, but it can also be produced from natural-gas condensates, petroleum distillates, and the fractional distillation of coal tar and peat.
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2-Naphthylamine or 2-aminonaphthalene is one of two isomeric aminonaphthalenes, compounds with the formula C 10 H 7 NH 2. It is a colorless solid, but samples take on a reddish color in air because of oxidation. It was formerly used to make azo dyes, but it is a known carcinogen and has largely been replaced by less toxic compounds. [2]