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The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Range (m sv /m su) Example g/dL m sv /m su; Very soluble <1 calcium nitrate: 158.7 0.63 Freely soluble 1 to 10 calcium chloride: 65 1.54 Soluble 10 to 30 sodium oxalate: 3.9 26 Sparingly soluble 30 to 100 Slightly soluble 100 to 1000 calcium sulfate: 0.21 490 Very slightly soluble 1000 to 10,000 dicalcium phosphate: 0.02 5000 Practically ...
Lead(II) sulfate is poorly soluble, as can be seen in the following diagram showing addition of SO 2− 4 to a solution containing 0.1 M of Pb 2+. The pH of the solution is 4.5, as above that, Pb 2+ concentration can never reach 0.1 M due to the formation of Pb(OH) 2. Observe that Pb 2+ solubility drops 10,000 fold as SO 2− 4 reaches 0.1 M.
For example, if there are 10 grams of salt (the solute) dissolved in 1 litre of water (the solvent), this solution has a certain salt concentration . If one adds 1 litre of water to this solution, the salt concentration is reduced. The diluted solution still contains 10 grams of salt (0.171 moles of NaCl).
The molar ionic strength, I, of a solution is a function of the concentration of all ions present in that solution. [3]= = where one half is because we are including both cations and anions, c i is the molar concentration of ion i (M, mol/L), z i is the charge number of that ion, and the sum is taken over all ions in the solution.
A water molecule in the first solvation shell of an aqua ion may exchange places with a water molecule in the bulk solvent. It is usually assumed that the rate-determining step is a dissociation reaction. [M(H 2 O) n] z+ → [M(H 2 O) n-1] z+ * + H 2 O. The * symbol signifies that this is the transition state in a chemical reaction. The rate of ...
When the pH of the solution is increased by adding an alkaline solution to it, the extent of hydrolysis increases. Measurements of pH or colour change are used to derive the equilibrium constant for the reaction. Further hydrolysis may occur, producing dimeric, trimeric or polymeric species containing hydroxy- or oxy- groups.
The drying agent absorbs any aerosolized water and/or water vapor (reaction 3.). The mix of the drying agent and NaOH absorbs the CO 2 and any water that may have been produced as a result of the absorption of the NaOH (reaction 4.). [11] The reactions are: Reaction 3 - absorption of water NaHCO 3 (aq) + H 2 SO 4 (aq) → CO 2 (g) + H 2 O(l ...