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Polyethylene was first synthesized by the German chemist Hans von Pechmann, who prepared it by accident in 1898 while investigating diazomethane. [12] [a] [13] [b] When his colleagues Eugen Bamberger and Friedrich Tschirner characterized the white, waxy substance that he had created, they recognized that it contained long −CH 2 − chains and termed it polymethylene.
HDPE is known for its high strength-to-density ratio. [4] The density of HDPE ranges from 930 to 970 kg/m 3. [5] Although the density of HDPE is only marginally higher than that of low-density polyethylene, HDPE has little branching, giving it stronger intermolecular forces and tensile strength (38 MPa versus 21 MPa) than LDPE. [6]
Expanded polyethylene copolymers (EPC) are also known - such as 50:50 (weight) materials with polystyrene. Though other properties are intermediate between the two bases, toughness for the copolymer exceeds either, with good tensile and puncture resistance. It is particularly applicable for re-usable products. [1]
LDPE has SPI resin ID code 4 Schematic of LDPE branching structure. Low-density polyethylene (LDPE) is a thermoplastic made from the monomer ethylene.It was the first grade of polyethylene, produced in 1933 by Dr John C. Swallow and M.W Perrin who were working for Imperial Chemical Industries (ICI) using a high pressure process via free radical polymerization. [1]
Medium-density polyethylene (MDPE) is a type of polyethylene defined by a density range of 0.926–0.940 g/cm 3. [1] It is less dense than HDPE, which is more common.. MDPE can be produced by chromium/silica catalysts, Ziegler-Natta catalysts or metallocene catalysts.
Ultra-high-molecular-weight polyethylene (UHMWPE, UHMW) is a subset of the thermoplastic polyethylene. Also known as high-modulus polyethylene ( HMPE ), it has extremely long chains, with a molecular mass usually between 3.5 and 7.5 million amu . [ 1 ]
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