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The rate of heat flow is the amount of heat that is transferred per unit of time in some material, usually measured in watts (joules per second). Heat is the flow of thermal energy driven by thermal non-equilibrium, so the term 'heat flow' is a redundancy (i.e. a pleonasm).
Flux F through a surface, dS is the differential vector area element, n is the unit normal to the surface. Left: No flux passes in the surface, the maximum amount flows normal to the surface.
The flow of heat is a form of energy transfer. Heat transfer is the natural process of moving energy to or from a system, other than by work or the transfer of matter. In a diathermal system, the internal energy can only be changed by the transfer of energy as heat: =.
Note that the thermodynamic relations for the internal energy and enthalpy are given by: = + = + We may also obtain an equation for the kinetic energy by taking the dot product of the Navier-Stokes equation with the flow velocity to yield: = + The second term on the righthand side may be expanded to read: = () With the aid of the thermodynamic relation for enthalpy and the last result, we may ...
Heat: Q: Thermal energy: joule (J) L 2 M T −2: Heat capacity: C p: Energy per unit temperature change J/K L 2 M T −2 Θ −1: extensive Heat flux density: ϕ Q: Heat flow per unit time per unit surface area W/m 2: M T −3: Illuminance: E v: Wavelength-weighted luminous flux per unit surface area lux (lx = cd⋅sr/m 2) L −2 J: Impedance: Z
(Note - the relation between pressure, volume, temperature, and particle number which is commonly called "the equation of state" is just one of many possible equations of state.) If we know all k+2 of the above equations of state, we may reconstitute the fundamental equation and recover all thermodynamic properties of the system.
This equation has been derived in the case of reversible changes. However, since U, S, and V are thermodynamic state functions that depend on only the initial and final states of a thermodynamic process, the above relation holds also for non-reversible changes.
In physics and engineering, heat flux or thermal flux, sometimes also referred to as heat flux density [1], heat-flow density or heat-flow rate intensity, is a flow of energy per unit area per unit time. Its SI units are watts per square metre (W/m 2). It has both a direction and a magnitude, and so it is a vector quantity.