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Due to the strong affinity towards self-condensation in alkaline media (see above) solutions of cyanamide are stabilized by the addition of 0.5 wt% of monosodium phosphate as buffer. Solid cyanamide is produced by careful evaporation of the solvent and subsequent addition of a hydrolysis-labile ester of formic acid. The ester absorbs traces of ...
The Frank–Caro process, also called cyanamide process, is the nitrogen fixation reaction of calcium carbide with nitrogen gas in a reactor vessel at about 1,000 °C. The reaction is exothermic and self-sustaining once the reaction temperature is reached. Originally the reaction took place in large steel cylinders with an electrical resistance ...
The Lewis diagram for NCN 2-showing the symmetric carbodiimide form (1) and the asymmetric cyanamide form (2). Inorganic carbodiimides (or cyanamides depending on the NCN 2-form) design a family of compounds containing the carbodiimide (or cyanamide) anion NCN 2-bonded to an inorganic group such as a metal.
Calcium cyanamide, also known as Calcium carbondiamide, Calcium cyan-2°-amide or Calcium cyanonitride is the inorganic compound with the formula CaCN 2. It is the calcium salt of the cyanamide (CN 2− 2) anion. This chemical is used as fertilizer [3] and is commercially known as nitrolime.
Sodium cyanide is a compound with the formula Na C N and the structure Na + − C≡N.It is a white, water-soluble solid. Cyanide has a high affinity for metals, which leads to the high toxicity of this salt.
Graphitic carbon nitride can be made by polymerization of cyanamide, dicyandiamide or melamine. The firstly formed polymeric C 3 N 4 structure, melon, with pendant amino groups, is a highly ordered polymer. Further reaction leads to more condensed and less defective C 3 N 4 species, based on tri-s-triazine (C 6 N 7) units as elementary building ...
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2-Cyanoguanidine is produced by treating cyanamide with base. It is produced in soil by decomposition of cyanamide. A variety of useful compounds are produced from 2-cyanoguanidine, guanidines and melamine. For example, acetoguanamine and benzoguanamine are prepared by condensation of cyanoguanidine with the nitrile: [2] [3]