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A polytropic process is a thermodynamic process that obeys the relation: = where p is the pressure , V is volume , n is the polytropic index , and C is a constant. The polytropic process equation describes expansion and compression processes which include heat transfer.
Sometimes the word polytrope may refer to an equation of state that looks similar to the thermodynamic relation above, although this is potentially confusing and is to be avoided. It is preferable to refer to the fluid itself (as opposed to the solution of the Lane–Emden equation) as a polytropic fluid or polytropic gas.
Polytropic compression will use a value of between 0 (a constant-pressure process) and infinity (a constant volume process). For the typical case where an effort is made to cool the gas compressed by an approximately adiabatic process, the value of n {\displaystyle n} will be between 1 and κ {\displaystyle \kappa } .
In this particular example, processes 1 and 3 are isothermal, whereas processes 2 and 4 are isochoric. The PV diagram is a particularly useful visualization of a quasi-static process, because the area under the curve of a process is the amount of work done by the system during that process.
[5] [6] The simplifying assumption frequently made is that a process is adiabatic. For example, the compression of a gas within a cylinder of an engine is assumed to occur so rapidly that on the time scale of the compression process, little of the system's energy can be transferred out as heat to the surroundings.
The work done in a process is the area beneath the process path on a P-V diagram. Figure 2 If the process is isobaric, then the work done on the piston is easily calculated. For example, if the gas expands slowly against the piston, the work done by the gas to raise the piston is the force F times the distance d.
In this process 1–2 the piston does work on the gas and in process 3–4 the gas does work on the piston during those isentropic compression and expansion processes, respectively. Processes 2–3 and 4–1 are isochoric processes; heat is transferred into the system from 2—3 and out of the system from 4–1 but no work is done on the system ...
This is the only type of static compression that liquids and gases can bear. [3] It affects the volume of the material, as quantified by the bulk modulus and the volumetric strain. The inverse process of compression is called decompression, dilation, or expansion, in which the object enlarges or increases in volume.