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In thermodynamics and chemical engineering, the vapor–liquid equilibrium (VLE) describes the distribution of a chemical species between the vapor phase and a liquid phase. The concentration of a vapor in contact with its liquid, especially at equilibrium , is often expressed in terms of vapor pressure , which will be a partial pressure (a ...
A McCabe–Thiele diagram for the distillation of a binary (two-component) feed is constructed using the vapor-liquid equilibrium (VLE) data—which is how vapor is concentrated when in contact with its liquid form—for the component with the lower boiling point. Figure 1: Typical McCabe–Thiele diagram for distillation of a binary feed
The definition of a w is where p is the partial water vapor pressure in equilibrium with the solution, and p* is the (partial) vapor pressure of pure water at the same temperature. An alternate definition can be a w ≡ l w x w {\displaystyle a_{w}\equiv l_{w}x_{w}} where l w is the activity coefficient of water and x w is the mole fraction of ...
The NRTL parameter set to use depends on the kind of phase equilibrium (i.e. solid–liquid (SL), liquid–liquid (LL), vapor–liquid (VL)). In the case of the description of a vapor–liquid equilibria it is necessary to know which saturated vapor pressure of the pure components was used and whether the gas phase was treated as an ideal or a ...
This should be kept in mind when using cubic equations in calculations, e.g., of vapor-liquid equilibrium. In 1972 G. Soave [ 4 ] replaced the 1 T {\textstyle {\frac {1}{\sqrt {T}}}} term of the Redlich–Kwong equation with a function α ( T , ω ) involving the temperature and the acentric factor (the resulting equation is also known as the ...
A hand boiler or (less commonly) love meter is a glass sculpture used as an experimental tool to demonstrate vapour-liquid equilibrium, or as a collector's item to whimsically "measure love." It consists of a lower bulb containing a volatile liquid and a mixture of gases that is connected usually by a twisting glass tube that connects to an ...
By adding a correction factor, known as the activity (, the activity of the i th component) to the liquid phase fraction of a liquid mixture, some of the effects of the real solution can be accounted for. The activity of a real chemical is a function of the thermodynamic state of the system, i.e. temperature and pressure.
Assume that the molar volume (V) is known from EOS calculations, and prior vapor-liquid equilibrium (VLE) calculations for mixtures. Then the two functions P h {\displaystyle P_{h}} and P a {\displaystyle P_{a}} can be utilized, and these functions are expected to be a more accurate and robust than the molar volume (V) itself.