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A cooling curve of naphthalene from liquid to solid. A cooling curve is a line graph that represents the change of phase of matter, typically from a gas to a solid or a liquid to a solid. The independent variable (X-axis) is time and the dependent variable (Y-axis) is temperature. [1] Below is an example of a cooling curve used in castings.
Taking this one stage further, the clue word can hint at the word or words to be abbreviated rather than giving the word itself. For example: "About" for C or CA (for "circa"), or RE. "Say" for EG, used to mean "for example". More obscure clue words of this variety include: "Model" for T, referring to the Model T.
The upper curve is the line of liquidus, and the lower curve is the line of solidus. In chemistry , materials science , and physics , the liquidus temperature specifies the temperature above which a material is completely liquid, [ 2 ] and the maximum temperature at which crystals can co-exist with the melt in thermodynamic equilibrium .
The pressure on a pressure-temperature diagram (such as the water phase diagram shown above) is the partial pressure of the substance in question. A phase diagram in physical chemistry , engineering , mineralogy , and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct ...
A typical phase diagram.The solid green line applies to most substances; the dashed green line gives the anomalous behavior of water. In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium. [1]
Retrieved from "https://en.wikipedia.org/w/index.php?title=Cooling_curves&oldid=264931021"This page was last edited on 18 January 2009, at 20:22 (UTC). (UTC).
As temperature falls to zero, the entropy of any pure crystalline substance tends to a universal constant. That is, lim T → 0 S = S 0 {\displaystyle \lim _{T\to 0}S=S_{0}} , where S 0 {\displaystyle S_{0}} is a universal constant that applies for all possible crystals, of all possible sizes, in all possible external constraints.
Thus, the liquid–liquid critical point in a two-component system must satisfy two conditions: the condition of the spinodal curve (the second derivative of the free energy with respect to concentration must equal zero), and the extremum condition (the third derivative of the free energy with respect to concentration must also equal zero or ...
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