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The spectrum of ice is similar to that of liquid water, with peak maxima at 3400 cm −1 (2.941 μm), 3220 cm −1 (3.105 μm) and 1620 cm −1 (6.17 μm) [14] In both liquid water and ice clusters, low-frequency vibrations occur, which involve the stretching (TS) or bending (TB) of intermolecular hydrogen bonds (O–H•••O).
Note the format of the parameter notation SXYab, where "S" stands for scattering parameter or S-parameter, "X" is the response mode (differential or common), "Y" is the stimulus mode (differential or common), "a" is the response (output) port and b is the stimulus (input) port. This is the typical nomenclature for scattering parameters.
However, water and ice absorb in infrared and close the infrared atmospheric window, thereby contributing to the greenhouse effect. The absorption spectrum of pure water is used in numerous applications, including light scattering and absorption by ice crystals and cloud water droplets , theories of the rainbow , determination of the single ...
A reason why Raman spectroscopy is useful in biological applications is because its results often do not face interference from water molecules, due to the fact that they have permanent dipole moments, and as a result, the Raman scattering cannot be picked up on. This is a large advantage, specifically in biological applications. [33]
Spectrophotometry is a tool that hinges on the quantitative analysis of molecules depending on how much light is absorbed by colored compounds. Important features of spectrophotometers are spectral bandwidth (the range of colors it can transmit through the test sample), the percentage of sample transmission, the logarithmic range of sample ...
In extremely pure water—as is found in mountain lakes, where scattering from particles is very low—the scattering from water molecules themselves also contributes a cyan color. [9] [10] Diffuse sky radiation due to Rayleigh scattering in the atmosphere along one's line of sight gives distant objects a cyan or light azure tint. This is most ...
The beam may display Brillouin scattering as a result of those vibrations, usually in the direction opposite the incoming beam, a phenomenon known as stimulated Brillouin scattering (SBS). For liquids and gases, the frequency shifts typically created are of the order of 1–10 GHz resulting in wavelength shifts of ~1–10 pm in the visible light.
Both Mie and Rayleigh scattering are considered elastic scattering processes, in which the energy (and thus wavelength and frequency) of the light is not substantially changed. However, electromagnetic radiation scattered by moving scattering centers does undergo a Doppler shift , which can be detected and used to measure the velocity of the ...