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Tantalum pentoxide (Ta 2 O 5) is the most important compound from the perspective of applications. Oxides of tantalum in lower oxidation states are numerous, including many defect structures, and are lightly studied or poorly characterized. [38] Tantalates, compounds containing [TaO 4] 3− or [TaO 3] − are numerous.
The pure tantalum hydrogen fluoride solution is then neutralised with aqueous ammonia to give hydrated tantalum oxide (Ta 2 O 5 (H 2 O) x), which is calcinated to tantalum pentoxide (Ta 2 O 5) as described in these idealized equations: [3] H 2 [TaF 7] + 5 H 2 O + 7 NH 3 → 1 / 2 Ta 2 O 5 (H 2 O) 5 + 7 NH 4 F Ta 2 O 5 (H 2 O) 5 → Ta 2 ...
Many oxides of tantalum are called tantalates. They are viewed as derivatives of "tantalic acid", hypothetic compounds with the formulas Ta 2 O 5 ·nH 2 O [1] or HTaO 3 [2]). Examples of such tantalates are lithium tantalate (LiTaO 3), lutetium tantalate (LuTaO 4), neodymium tantalate (NdTaO 4) and lead scandium tantalate (PST or Pb(Sc x Ta 1-x ...
[4] 2 Ta + 5 Cl 2 → 2 TaCl 5 2 Ta + 10 HCl → 2 TaCl 5 + 5 H 2. It can also be prepared by a reaction between tantalum pentoxide and thionyl chloride at 240 °C Ta 2 O 5 + 5 SOCl 2 → 2 TaCl 5 + 5 SO 2. Tantalum pentachloride is commercially available, however samples can be contaminated with tantalum(V) oxychloride (TaOCl 3), formed by ...
Single crystals of TaB, Ta 5 B 6, Ta 3 B 4 or TaB 2 (about 1 cm diameter, 6 cm length) can be produced by the floating zone method. [2] [3]Tantalum boride films can be deposited from a gas mixture of TaCl 5-BCl 3-H 2-Ar in the temperature range 540–800 °C.
2 H 2 [NbOF 5] + 10 NH 4 OH → Nb 2 O 5 ↓ + 10 NH 4 F + 7 H 2 O. Several methods are used for the reduction to metallic niobium. The electrolysis of a molten mixture of K 2 [NbOF 5] and sodium chloride is one; the other is the reduction of the fluoride with sodium. With this method, a relatively high purity niobium can be obtained.
The mineral group tantalite [(Fe, Mn)Ta 2 O 6] is the primary source of the chemical element tantalum, a corrosion (heat and acid) resistant metal.It is chemically similar to columbite, and the two are often grouped together as a semi-singular mineral called coltan or "columbite-tantalite" in many mineral guides.
Tantalum(IV) sulfide is an inorganic compound with the formula Ta S 2. It is a layered compound with three-coordinate sulfide centres and trigonal prismatic or octahedral metal centres. [ 2 ] It is structurally similar to molybdenum disulfide MoS 2 , and numerous other transition metal dichalcogenides .