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The Mpemba effect is the name given to the observation that a liquid (typically water) that is initially hot can freeze faster than the same liquid which begins cold, under otherwise similar conditions. There is disagreement about its theoretical basis and the parameters required to produce the effect.
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During the final stage of freezing, an ice drop develops a pointy tip, which is not observed for most other liquids, and arises because water expands as it freezes. [10] Once the liquid is completely frozen, the sharp tip of the drop attracts water vapor in the air, much like a sharp metal lightning rod attracts electrical charges. [10]
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Most liquids freeze by crystallization, formation of crystalline solid from the uniform liquid. This is a first-order thermodynamic phase transition, which means that as long as solid and liquid coexist, the temperature of the whole system remains very nearly equal to the melting point due to the slow removal of heat when in contact with air, which is a poor heat conductor.
These ice particles end up as the nuclei of larger ice crystals. This process only happens at temperatures between 0 °C (32 °F) and −40 °C (−40 °F). Below −40 °C (−40 °F), liquid water will spontaneously nucleate, and freeze. The surface tension of the water allows the droplet to stay liquid well below its normal freezing point.