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Formally, a carbanion is the conjugate base of a carbon acid: R 3 CH + B − → R 3 C − + HB. where B stands for the base. The carbanions formed from deprotonation of alkanes (at an sp 3 carbon), alkenes (at an sp 2 carbon), arenes (at an sp 2 carbon), and alkynes (at an sp carbon) are known as alkyl, alkenyl , aryl, and alkynyl anions ...
C 5 F 6 O 3: hexafluoroglutaric acid anhydride: 376-68-1 C 5 F 8 O 2: hexafluoroglutaryl fluoride: 678-78-4 C 5 F 10: decafluorocyclopentane: 376-77-2 C 5 F 11 N: undecafluoropiperidine: 836-77-1 C 5 F 13 N: perfluoromethyldiethylamine: 758-48-5 C 5 FeO 4 S: tetracarbonyl carbonothioyl iron: 66517-47-3 C 5 FeO 5: iron pentacarbonyl: 13463-40-6 ...
Such an atom has the following electron configuration: s 2 p 5; this requires only one additional valence electron to form a closed shell. To form an ionic bond, a halogen atom can remove an electron from another atom in order to form an anion (e.g., F −, Cl −, etc.). To form a covalent bond, one electron from the halogen and one electron ...
Thus, each sulfur atom is hexavalent or has valence 6, but has oxidation state +5. In the dioxygen molecule O 2, each oxygen atom has 2 valence bonds and so is divalent (valence 2), but has oxidation state 0. In acetylene H−C≡C−H, each carbon atom has 4 valence bonds (1 single bond with hydrogen atom and a triple bond with the other ...
The hydrogen anion, with its loosely held two-electron cloud, has a larger radius than the neutral atom, which in turn is much larger than the bare proton of the cation. Hydrogen forms the only charge-+1 cation that has no electrons, but even cations that (unlike hydrogen) retain one or more electrons are still smaller than the neutral atoms or ...
Carbon-14 is formed in upper layers of the troposphere and the stratosphere at altitudes of 9–15 km by a reaction that is precipitated by cosmic rays. [66] Thermal neutrons are produced that collide with the nuclei of nitrogen-14, forming carbon-14 and a proton. As such, 1.5% × 10 −10 of atmospheric carbon dioxide contains carbon-14. [67]
For the cyclopentadienyl anion C 5 H − 5, the oxidation state of C is −1 + − 1 / 5 = − 6 / 5 . The −1 occurs because each carbon is bonded to one hydrogen atom (a less electronegative element), and the − 1 / 5 because the total ionic charge of −1 is divided among five equivalent carbons. Again this can be ...
Other more exotic carbon–oxygen anions exist, such as acetylenedicarboxylate (O 2 C–C≡C–CO 2 2−), mellitate (C 12 O 9 6−), squarate (C 4 O 4 2−), and rhodizonate (C 6 O 6 2−). The anhydrides of some of these acids are oxides of carbon; carbon dioxide, for instance, can be seen as the anhydride of carbonic acid.