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Potassium manganate is the inorganic compound with the formula K 2 MnO 4. This green-colored salt is an intermediate in the industrial synthesis of potassium permanganate (KMnO 4), a common chemical. [1] Occasionally, potassium manganate and potassium permanganate are confused, but each compound's properties are distinct.
A permanganate (/ p ər ˈ m æ ŋ ɡ ə n eɪ t, p ɜːr-/) [1] is a chemical compound with the manganate(VII) ion, MnO − 4, the conjugate base of permanganic acid. Because the manganese atom has a +7 oxidation state, the permanganate(VII) ion is a strong oxidising agent. The ion is a transition metal ion with a tetrahedral structure. [2]
The value determined is known as the permanganate value. In analytical chemistry, a standardized aqueous solution of KMnO 4 is sometimes used as an oxidizing titrant for redox titrations (permanganometry). As potassium permanganate is titrated, the solution becomes a light shade of purple, which darkens as excess of the titrant is added to the ...
Solution containing the manganate(VI) ion. The manganate(VI) ion is tetrahedral, similar to sulfate or chromate: indeed, manganates are often isostructural with sulfates and chromates, a fact first noted by Eilhard Mitscherlich in 1831. [5] The manganese–oxygen distance is 165.9 pm, about 3 pm longer than in permanganate. [5]
Similar to potassium permanganate, the two-step decomposition of caesium permanganate leads to the formation of caesium manganate intermediates. It breaks down into manganese dioxide, caesium oxide and oxygen. [5] The decomposition temperature is between 200 and 300 °C. [6] Drift-away oxygen caused an 8% mass loss in the product. [6]
The biggest difference between the two chemicals is that potassium permanganate is less soluble than sodium permanganate. [5] Potassium permanganate is a crystalline solid that is typically dissolved in water before application to the contaminated site. [3] Unfortunately, the solubility of potassium permanganate is dependent on temperature.
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Aside from various permanganate salts, Mn(VII) is represented by the unstable, volatile derivative Mn 2 O 7. Oxyhalides (MnO 3 F and MnO 3 Cl) are powerful oxidizing agents. [11] The most prominent example of Mn in the +6 oxidation state is the green anion manganate, [MnO 4] 2−. Manganate salts are intermediates in the extraction of manganese ...