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Water molecules stay close to each other , due to the collective action of hydrogen bonds between water molecules. These hydrogen bonds are constantly breaking, with new bonds being formed with different water molecules; but at any given time in a sample of liquid water, a large portion of the molecules are held together by such bonds. [61]
The atomic mass, on the other hand, is measured using the atomic mass unit based on the mass of the carbon-12 atom. It is denoted with symbols "u" (for unified atomic mass unit) or "Da" (for dalton). The atomic masses of naturally occurring isotopes of an element determine the standard atomic weight of the element.
This is because hydrogen atoms (1 H and 2 H) are rapidly exchanged between water molecules. Water containing 50% 1 H and 50% 2 H in its hydrogen, is actually about 50% HDO and 25% each of H 2 O and D 2 O, in dynamic equilibrium. In normal water, about 1 molecule in 3,200 is HDO (one hydrogen in 6,400 is 2 H), and heavy water molecules (D
The standard atomic weight takes into account the isotopic distribution of the element in a given sample (usually assumed to be "normal"). For example, water has a molar mass of 18.0153(3) g/mol, but individual water molecules have molecular masses which range between 18.010 564 6863(15) Da (1 H 2 16 O) and 22.027 7364(9) Da (2 H 2 18 O).
The molar mass of atoms of an element is given by the relative atomic mass of the element multiplied by the molar mass constant, M u ≈ 1.000 000 × 10 −3 kg/mol ≈ 1 g/mol. For normal samples from Earth with typical isotope composition, the atomic weight can be approximated by the standard atomic weight [2] or the conventional atomic weight.
Water molecules carry unique isotopic "fingerprints", based in part on differing ratios of the oxygen and hydrogen isotopes that constitute the water molecule. Isotopes are atoms of the same element that have a different number of neutrons in their nuclei. Air, freshwater and seawater contain mostly oxygen-16 ( 16 O). Oxygen-18 (18 O) occurs in ...
Thus, the atomic mass of a carbon-12 atom is 12 Da by definition, but the relative isotopic mass of a carbon-12 atom is simply 12. The sum of relative isotopic masses of all atoms in a molecule is the relative molecular mass. The atomic mass of an isotope and the relative isotopic mass refers to a certain specific isotope of an element.
An example is water, whose hydrogen-related isotopologues are: "light water" (HOH or H 2 O), "semi-heavy water" with the deuterium isotope in equal proportion to protium (HDO or 1 H 2 HO), "heavy water" with two deuterium atoms (D 2 O or 2 H 2 O); and "super-heavy water" or tritiated water (T 2 O or 3 H 2 O, as well as HTO [1 H 3 HO] and DTO [2 ...