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He became known for the discovery of the phosphate of soda, and the process of lime softening of hard water the 'Clark process'. A Clark degree (°Clark) of water hardness is defined as one grain (64.8 mg) of CaCO 3 per Imperial gallon (4.55 litres) of water, equivalent to 14.254 ppm. and 10^5 parts of water
The grain per gallon (gpg) is a unit of water hardness defined as 1 grain (64.8 milligrams) of calcium carbonate dissolved in 1 US gallon of water (3.785412 L). It translates into 1 part in about 58,000 parts of water or 17.1 parts per million (ppm). Also called Clark degree (in terms of an imperial gallon).
Lime softening (also known as lime buttering, lime-soda treatment, or Clark's process) [1] is a type of water treatment used for water softening, which uses the addition of limewater (calcium hydroxide) to remove hardness (deposits of calcium and magnesium salts) by precipitation.
The most common means for removing water hardness rely on ion-exchange resin or reverse osmosis. Other approaches include precipitation methods, such as fluidized bed pellet softening, [6] and sequestration by the addition of chelating agents. Distillation and reverse osmosis are the most widely used two non-chemical methods of water softening.
In water testing hardness is often measured in parts per million (ppm), where one part per million is defined as one milligram of calcium carbonate (CaCO 3) per litre of water. Consequently, 1 dGH corresponds to 10 ppm CaO but 17.848 ppm CaCO 3 which has a molar mass of 100.09 g/mol.
The permanent hardness of water is determined by the water's concentration of cations with charges greater than or equal to 2+. Usually, the cations have a charge of 2+, i.e., they are divalent . Common cations found in hard water include Ca 2+ and Mg 2+ , which frequently enter water supplies by leaching from minerals within aquifers .
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