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The placard displays UN number 1129, indicating butyraldehyde, as well as the pictogram for a flammable liquid. [27] Materials on Table 2, which is all other hazardous materials not in Table 1, [j] must display placard if 1,001 pounds (454 kg) or more of the material is loaded into a vehicle. If 1,000 pounds (450 kg) or less of a Table 2 ...
"Dangerous goods" (also known as "hazardous materials" or "HAZMAT" in the United States) may be a pure chemical substance (e.g. TNT, nitroglycerin), mixtures (e.g. dynamite, gunpowder) or manufactured articles (e.g. ammunition, fireworks). The transport hazards that they pose are grouped into nine classes, which may be subdivided into divisions ...
The material is forbidden from being offered for transportation according to 49CFR 172.101 of this subchapter or 49CFR 173.21; The Associate Administrator for Hazardous Materials Safety has determined that the material does not present a hazard which is associated with a Division 5.2 material; or; The material meets one of the following conditions:
A hazardous material, as defined by the Secretary, is any particular quantity or form of a material that may pose an unreasonable risk to health and safety or property during transportation in commerce. [7] This includes materials that are explosive, radioactive, infectious, flammable, toxic, oxidizing, or corrosive.
Following the UN model, the DOT divides regulated hazardous materials into nine classes, some of which are further subdivided. Hazardous materials in transportation must be placarded and have specified packaging and labelling. Some materials must always be placarded, others may only require placarding in certain circumstances. [23]
Materials may react violently with water or form peroxides upon exposure to air (e.g., potassium, sodium). 1. Materials that are normally stable but can become unstable (self-react) at high temperatures and pressures. Materials may react non-violently with water or undergo hazardous polymerization in the absence of inhibitors (e.g., propene). 0.
The GHS transport pictograms are the same as those recommended in the UN Recommendations on the Transport of Dangerous Goods, widely implemented in national regulations such as the U.S. Federal Hazardous Materials Transportation Act (49 U.S.C. 5101–5128) and D.O.T. regulations at 49 C.F.R. 100–185.
Note 2: A liquid in Division 6.1 meeting criteria for Packing Group I, Hazard Zones A or B stated in paragraph (a)(2) of this section is a material poisonous by inhalation subject to the additional hazard communication requirements in 49CFR 172.203(m)(3), 49CFR 172.313 and Table 1 of 49CFR 172.504(e) of this subchapter.
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