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The dependence on m correlates with the oxidation state of the central atom, X: the higher the oxidation state the stronger the oxyacid. For example, p K a for HClO is 7.2, for HClO 2 is 2.0, for HClO 3 is −1 and HClO 4 is a strong acid ( p K a ≪ 0 ). [ 7 ]
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the Van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
For strongly temperature-dependent α, this approximation is only useful for small temperature differences ΔT. Temperature coefficients are specified for various applications, including electric and magnetic properties of materials as well as reactivity. The temperature coefficient of most of the reactions lies between 2 and 3.
In chemistry and biochemistry, the Henderson–Hasselbalch equation = + ([] []) relates the pH of a chemical solution of a weak acid to the numerical value of the acid dissociation constant, K a, of acid and the ratio of the concentrations, [] [] of the acid and its conjugate base in an equilibrium.
In chemistry, biochemistry, and pharmacology, a dissociation constant (K D) is a specific type of equilibrium constant that measures the propensity of a larger object to separate (dissociate) reversibly into smaller components, as when a complex falls apart into its component molecules, or when a salt splits up into its component ions.
where ln denotes the natural logarithm, is the thermodynamic equilibrium constant, and R is the ideal gas constant.This equation is exact at any one temperature and all pressures, derived from the requirement that the Gibbs free energy of reaction be stationary in a state of chemical equilibrium.
The pH-dependence of the activity displayed by enzymes and the pH-dependence of protein stability, for example, are properties that are determined by the pK a values of amino acid side chains. The p K a values of an amino acid side chain in solution is typically inferred from the p K a values of model compounds (compounds that are similar to ...
Chemical formula. C 8 H 10 N 4 O 2: Molar mass: ... data relate to Standard temperature and pressure. ... This page was last edited on 30 October 2024, ...