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The physical manifestation of leaving group ability is the rate at which a reaction takes place. Good leaving groups give fast reactions. By transition state theory, this implies that reactions involving good leaving groups have low activation barriers leading to relatively stable transition states.
Each group is named by Small Groups library as G o i, where o is the order of the group, and i is the index used to label the group within that order. Common group names: Z n: the cyclic group of order n (the notation C n is also used; it is isomorphic to the additive group of Z/nZ) Dih n: the dihedral group of order 2n (often the notation D n ...
The strength of the water cycle and its changes over time are of considerable interest, especially as the climate changes. [5] The hydrological cycle is a system whereby the evaporation of moisture in one place leads to precipitation (rain or snow) in another place.
The driving mechanism for micellization is the transfer of hydrocarbon chains from water into the oil-like interior. This entropic effect is called the hydrophobic effect. Compared to the increase of entropy of the surrounding water molecules, this hydrophobic interaction is relatively small. The water molecules are highly ordered around the ...
The loss of the intercranial joint was a direct functional necessity to strengthen the broad and long platybasic skull when the animal was out of the water. [2] The tubular lower jaw of the Elginerpeton , compared to the flat-lamina jaw shape of fishes gave it superior cross-sectional force, required when not supported in an aquatic setting ...
The transition from solid to liquid, and gas to liquid (shown by the white condensed water vapour). Other phase changes include: Transition to a mesophase between solid and liquid, such as one of the "liquid crystal" phases. The dependence of the adsorption geometry on coverage and temperature, such as for hydrogen on iron (110).
Stratification in water is the formation in a body of water of relatively distinct and stable layers by density. It occurs in all water bodies where there is stable density variation with depth. Stratification is a barrier to the vertical mixing of water, which affects the exchange of heat, carbon, oxygen and nutrients. [1]
The water cycle is essential to life on Earth and plays a large role in the global climate system and ocean circulation. The warming of our planet is expected to be accompanied by changes in the water cycle for various reasons. [24] For example, a warmer atmosphere can contain more water vapor which has effects on evaporation and rainfall.