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Pure lime is soluble in water containing carbonic acid, a natural, weak acid which is a solution of carbon dioxide in water and acid rain so it will slowly wash away, but this characteristic also produces autogenous or self-healing process where the dissolved lime can flow into cracks in the material and be redeposited, automatically repairing ...
Rotary lime kiln (rust-colored horizontal tube at right) with preheater, Wyoming, 2010 Traditional lime kiln in Sri Lanka. A lime kiln is a kiln used for the calcination of limestone (calcium carbonate) to produce the form of lime called quicklime (calcium oxide). The chemical equation for this reaction is: CaCO 3 + heat → CaO + CO 2
Soda lime canister used in anaesthetic machines to act as a carbon dioxide scrubber. Soda lime, a mixture of sodium hydroxide (NaOH) and calcium oxide (CaO), is used in granular form within recirculating breathing environments like general anesthesia and its breathing circuit, submarines, rebreathers, and hyperbaric chambers and underwater habitats.
As lime in the form of limewater is added to raw water, the pH is raised and the equilibrium of carbonate species in the water is shifted. Dissolved carbon dioxide (CO 2) is changed into bicarbonate (HCO − 3) and then carbonate (CO 2-3). This action causes calcium carbonate to precipitate due to exceeding the solubility product.
The carbon dioxide in the air reacts with the alkali in the cement and makes the pore water more acidic, thus lowering the pH. Carbon dioxide will start to carbonatate the cement in the concrete from the moment the object is made. This carbonatation process will start at the surface, then slowly moves deeper and deeper into the concrete.
This contrasts with calcium hydroxide, also called slaked lime or air lime that is used to make lime mortar, the other common type of lime mortar, which sets by carbonation (re-absorbing carbon dioxide (CO 2) from the air). Hydraulic lime provides a faster initial set and higher compressive strength than air lime, and hydraulic lime will set in ...
However, there is an equilibrium between dissolved calcium bicarbonate and dissolved calcium carbonate as represented by the chemical equation Ca 2+ + 2 HCO − 3 ⇌ Ca 2+ + CO 2− 3 + CO 2 + H 2 O. Note that CO 2 is dissolved in the water. Carbon dioxide dissolved in water (aq) tends to equilibrate with carbon dioxide in the gaseous state (g ...
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