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The Journal of the American Chemical Society (also known as JACS) is a weekly peer-reviewed scientific journal that was established in 1879 by the American Chemical Society. [1] The journal has absorbed two other publications in its history, the Journal of Analytical and Applied Chemistry (July 1893) and the American Chemical Journal (January ...
The Johnson–Corey–Chaykovsky reaction (sometimes referred to as the Corey–Chaykovsky reaction or CCR) is a chemical reaction used in organic chemistry for the synthesis of epoxides, aziridines, and cyclopropanes. It was discovered in 1961 by A. William Johnson and developed significantly by E. J. Corey and Michael Chaykovsky
The Journal of the American Oil Chemists' Society is a peer-reviewed scientific journal published by Wiley [1] and the American Oil Chemists' Society.The journal publishes original research articles, letters, and invited reviews in the area of science and technology of oils, fats, oilseed proteins, and related materials.
The ACS Style Guide: Effective Communication of Scientific Information. 3rd ed. American Chemical Society, 2006. doi : 10.1021/bk-2006-STYG . ISBN 9780841239999 .
In organic chemistry, the Hammett equation describes a linear free-energy relationship relating reaction rates and equilibrium constants for many reactions involving benzoic acid derivatives with meta- and para-substituents to each other with just two parameters: a substituent constant and a reaction constant.
The Stetter reaction is a reaction used in organic chemistry to form carbon-carbon bonds through a 1,4-addition reaction utilizing a nucleophilic catalyst. [1] While the related 1,2-addition reaction, the benzoin condensation, was known since the 1830s, the Stetter reaction was not reported until 1973 by Dr. Hermann Stetter. [2]
These conditions result in the formation of the (−)-enantiomer of the aryl ether in 72% chemical yield and 88% enantiomeric excess. Trost AAA galantamine intermediate synthesis. Another Tsuji–Trost reaction was used during the initial stages of the synthesis of (−)-neothiobinupharidine.
A (4+3) cycloaddition [1] is a cycloaddition between a four-atom π-system and a three-atom π-system to form a seven-membered ring. Allyl or oxyallyl cations (propenylium-2-olate) are commonly used three-atom π-systems, while a diene (such as butadiene) plays the role of the four-atom π-system.