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Nitrocellulose film on a light box, showing deterioration, from Library and Archives Canada collection. In 1855, the first human-made plastic, nitrocellulose (branded Parkesine, patented in 1862), was created by Alexander Parkes from cellulose treated with nitric acid and a solvent.
Celluloids are a class of materials produced by mixing nitrocellulose and camphor, often with added dyes and other agents.Once much more common for its use as photographic film before the advent of safer methods, celluloid's common present-day uses are for manufacturing table tennis balls, musical instruments, combs, office equipment, fountain pen bodies, and guitar picks.
Nitrocellulose is a derivative of cellulose that is soluble in organic solvents. It is mainly used as an explosive or as a lacquer. Many early plastics, including celluloid, were made from nitrocellulose. Cellulose acetate shares many traits with viscose rayon and was formerly considered the same textile. However, rayon resists heat, while ...
Cellulose acetate and cellulose triacetate are film- and fiber-forming materials that find a variety of uses. Nitrocellulose was initially used as an explosive and was an early film forming material. When plasticized with camphor, nitrocellulose gives celluloid. Cellulose Ether [54] derivatives include:
Nitrocellulose is guncotton, the first replacement propellant for gun powder in firearms. A can of decomposing nitrate film Film stock with a nitrate base was the first transparent flexible plasticized base commercially available, thanks to celluloid developments by John Carbutt , Hannibal Goodwin , and Eastman Kodak in the 1880s.
In 1884, Paul Vieille invented a smokeless powder called Poudre B (short for poudre blanche, white powder, as distinguished from black powder) [7]: 289–292 made from 68.2% insoluble nitrocellulose, 29.8% soluble nitrocellulose gelatinized with ether and 2% paraffin. This was adopted for the Lebel rifle chambered in 8×50mmR Lebel.
The first practical nitrocellulose enamel Glossy White S.2567, still for interior use, was introduced in 1919 in the UK by Nobel Explosives. [26] In 1923, General Motors' Oakland brand automobile was the first to introduce one of the new fast-drying nitrocellulose lacquers, a bright blue, produced by DuPont under their Duco tradename.
Although earlier temporary pontoon bridges had been made in China, the first secure and permanent ones (and linked with iron chains) in China came first during the Qin dynasty (221 BC–207 BC). The later Song dynasty (960–1279 AD) Chinese statesman Cao Cheng once wrote a description of the early pontoon bridges in China. [386]