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Absolute zero is the lowest limit of the thermodynamic temperature scale; a state at which the enthalpy and entropy of a cooled ideal gas reach their minimum value. The fundamental particles of nature have minimum vibrational motion, retaining only quantum mechanical, zero-point energy -induced particle motion.
At absolute zero (zero kelvins) the system must be in a state with the minimum possible energy. Entropy is related to the number of accessible microstates, and there is typically one unique state (called the ground state) with minimum energy. [1] In such a case, the entropy at absolute zero will be exactly zero.
At absolute zero temperature, the system is in the state with the minimum thermal energy, the ground state. The constant value (not necessarily zero) of entropy at this point is called the residual entropy of the system. With the exception of non-crystalline solids (e.g. glass) the residual entropy of a system is typically close to zero. [2]
The numerical zero of a temperature scale is not bound to the absolute zero of temperature. Nevertheless, some temperature scales have their numerical zero coincident with the absolute zero of temperature. Examples are the International SI temperature scale, the Rankine temperature scale, and the thermodynamic temperature scale. Other ...
Its numerical zero point, 0 K, is at the absolute zero of temperature. Since May 2019, the kelvin has been defined through particle kinetic theory , and statistical mechanics. In the International System of Units (SI), the magnitude of the kelvin is defined in terms of the Boltzmann constant , the value of which is defined as fixed by ...
An absolute scale can only be applied to measurements in which a true minimum is known to exist. Time, for example, which does not have a clearly known beginning, is measured on a relative scale, with an arbitrary zero-point such as the conventional date of the birth of Jesus (see Anno Domini) or the accession of an emperor.
In condensed matter physics, a Bose–Einstein condensate (BEC) is a state of matter that is typically formed when a gas of bosons at very low densities is cooled to temperatures very close to absolute zero, i.e., 0 K (−273.15 °C; −459.67 °F).
Residual entropy is the difference in entropy between a non-equilibrium state and crystal state of a substance close to absolute zero.This term is used in condensed matter physics to describe the entropy at zero kelvin of a glass or plastic crystal referred to the crystal state, whose entropy is zero according to the third law of thermodynamics.