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The last equation above fixes the concentration of dissolved CO 2 as a function of P CO 2, independent of the concentration of dissolved CaCO 3. At atmospheric partial pressure of CO 2, dissolved CO 2 concentration is 1.2 × 10 −5 moles per liter. The equation before that fixes the concentration of H 2 CO 3 as a function of CO 2 concentration.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
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As calculated by the Henderson–Hasselbalch equation, in order to maintain a normal pH of 7.4 in the blood (whereby the pK a of carbonic acid is 6.1 at physiological temperature), a 20:1 ratio of bicarbonate to carbonic acid must constantly be maintained; this homeostasis is mainly mediated by pH sensors in the medulla oblongata of the brain ...
Thus the chemical equation for alkalinity in seawater is: A T = [HCO 3 −] + 2[CO 3 2-] + [B(OH) 4 −] There are many methods of alkalinity generation in the ocean. Perhaps the most well known is the dissolution of calcium carbonate to form Ca 2+ and CO 2− 3 (carbonate). The carbonate ion has the potential to absorb two hydrogen ions.
The aquatic inorganic carbon system is composed of the various ionic, dissolved, solid, and/or gaseous forms of carbon dioxide in water. These species include dissolved carbon dioxide, carbonic acid, bicarbonate anion, carbonate anion, calcium carbonate, magnesium carbonate, and others.
For a gas, it is the hypothetical state the gas would assume if it obeyed the ideal gas equation at a pressure of 1 bar. For a gaseous or solid solute present in a diluted ideal solution , the standard state is the hypothetical state of concentration of the solute of exactly one mole per liter (1 M ) at a pressure of 1 bar extrapolated from ...
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).