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Aqua regia is primarily used to produce chloroauric acid, the electrolyte in the Wohlwill process for refining the highest purity (99.999%) gold. Aqua regia is also used in etching and in specific analytic procedures. It is also used in some laboratories to clean glassware of organic compounds and metal particles.
Generally, the preparation of this material involves gold being dissolved in aqua regia, then reacted with a solution of tin(II) chloride. The tin(II) chloride reduces the chloroauric acid from the dissolution of gold in aqua regia to a colloid of elemental gold supported on tin dioxide to give a purple precipitate or coloration.
Silver was removed by filtering and gold was then recovered by evaporating the liquid and heating the residue. Nitric acid was suitable for separating small quantities of gold from silver and aqua regia used to separate small quantities of silver from gold. Aqua regia acid process is used by refiners of scrap gold used in jewelry manufacturing.
1.3 Chemical reactions. 2 Production. 3 Uses. 4 Health effects and safety. 5 References. ... Chloroauric acid is produced by dissolving gold in aqua regia ...
Fulminating gold – a number of gold based explosives which "fulminate", or detonate easily. – gold hydrazide, formed by adding ammonia to the auric hydroxide. When dry, can explode on concussion. – an unstable gold carbonate formed by precipitation by potash from gold dissolved in aqua regia. Galena – lead(II) sulfide. Lead ore.
Chloro(dimethyl sulfide)gold(I) is commercially available. It may be prepared by dissolving gold in aqua regia (to give chloroauric acid), followed by addition of dimethyl sulfide. [2] Alternatively, sodium tetrachloroaurate may be used as the source of gold(III). [3] The bromo analog, Me 2 SAuBr, has also been synthesized by a similar route. [4]
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Gold is unaffected by most acids. It does not react with hydrofluoric, hydrochloric, hydrobromic, hydriodic, sulfuric, or nitric acid. It does react with selenic acid, and is dissolved by aqua regia, a 1:3 mixture of nitric acid and hydrochloric acid. Nitric acid oxidizes the metal to +3 ions, but only in minute amounts, typically undetectable ...