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Sulfuryl fluoride (also spelled sulphuryl fluoride) is an inorganic compound with the formula SO 2 F 2. It is an easily condensed gas and has properties more similar to sulfur hexafluoride than sulfuryl chloride , being resistant to hydrolysis even up to 150 °C. [ 3 ]
Perfluorooctanesulfonyl derivatives, such as PFOS, are produced from their sulfonyl fluoride, which are produced by electrofluorination [14] In the molecular biology, sulfonyl fluorides are used to label proteins. They specifically react with serine, threonine, tyrosine, lysine, cysteine, and histidine residues. The fluorides are more resistant ...
The sulfonyl functional group (RS(O) 2 R') has become an important electron-withdrawing group for modern organic chemistry. α-Sulfonyl carbanions may be used as nucleophiles in alkylation reactions, Michael-type additions, and other processes. [3] After having served their synthetic purpose, sulfonyl groups are often removed.
Zinc fluoride is an inorganic chemical compound with the chemical formula Zn F 2. It is encountered as the anhydrous form and also as the tetrahydrate, ZnF 2 ·4H 2 O (rhombohedral crystal structure). [2] It has a high melting point and has the rutile structure containing 6 coordinate zinc, which suggests appreciable ionic character in its ...
Trimethylsilyl enol ethers react with NfF in the presence of a substoichiometric fluoride source at 0 °C to ambient temperature to give alkenyl nonaflates in moderate to good yields. Dried tetra-n-butylammonium fluoride was the preferred fluoride source in one study, [6] but CsF has been used in difficult cases with excellent results. [7]
A palladium acetate catalysed reaction described in 1982 used zinc powder with the main intermediate believed to be CF 3 ZnI with Pd(0) is the active catalyst. [ 35 ] [ 36 ] The first copper catalysed coupling was reported in 2009 and based on an iodoarene , a trifluoromethylsilane , copper iodide and 1,10-phenanthroline . [ 37 ]
The noble metals ruthenium, rhodium, palladium, platinum, and gold react least readily, requiring pure fluorine gas at 300–450 °C (575–850 °F). [14] Fluorine reacts explosively with hydrogen in a manner similar to that of alkali metals. [15] The halogens react readily with fluorine gas [16] as does the heavy noble gas radon. [17]
Carbonyl compounds generally react with SF 4 to yield geminal difluorides. Reaction times tend to be on the order of hours and yields are moderate. [7] Fluorination of lactones can provide heterocyclic fluorides, although ring opening has been observed for γ-butyrolactone. The six-membered lactide does not experience ring opening. [8]