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m is the molar conductivity at infinite dilution (or limiting molar conductivity), which can be determined by extrapolation of Λ m as a function of √ c, K is the Kohlrausch coefficient, which depends mainly on the stoichiometry of the specific salt in solution, α is the dissociation degree even for strong concentrated electrolytes,
where + and are the numbers of cations and anions respectively per formula unit of electrolyte. [2] In practice the molar ionic conductivities are calculated from the measured ion transport numbers and the total molar conductivity.
The conductivity of a solution of a strong electrolyte at low concentration follows Kohlrausch's Law = where Λ 0 m is known as the limiting molar conductivity, K is an empirical constant and c is the electrolyte concentration. (Limiting here means "at the limit of the infinite dilution".)
The Ostwald law of dilution provides a satisfactory description of the concentration dependence of the conductivity of weak electrolytes like CH 3 COOH and NH 4 OH. [3] [4] The variation of molar conductivity is essentially due to the incomplete dissociation of weak electrolytes into ions.
Electrical conductivity of water samples is used as an indicator of how salt-free, ion-free, or impurity-free the sample is; the purer the water, the lower the conductivity (the higher the resistivity). Conductivity measurements in water are often reported as specific conductance, relative to the conductivity of pure water at 25 °C.
Chemical formula. KCl Molar mass: 74.555 g·mol −1 Appearance white crystalline solid Odor: odorless ... Thermal conductivity = 0.036 W/(cm·K)
The molar ionic strength, I, of a solution is a function of the concentration of all ions present in that solution. [3]= = where one half is because we are including both cations and anions, c i is the molar concentration of ion i (M, mol/L), z i is the charge number of that ion, and the sum is taken over all ions in the solution.
Many devices handle and manipulate large amounts of energy in small volumes and at high speeds, so due to the electrically insulating nature and high thermal conductivity of AlN, it becomes a potential material for high-power power electronics. Among group III-nitride materials, AlN has higher thermal conductivity compared to gallium nitride ...