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The Wohlwill process is an industrial-scale chemical procedure used to refine gold to the highest degree of purity (99.999%). [1] The process was invented in 1874 by Emil Wohlwill. This electrochemical process involves using a cast gold ingot, often called a doré bar, of 95%+ gold to serve as an anode.
Invented by Emil Wohlwill in 1874, the Wohlwill process produces the highest purity gold (99.999%). It is an electrolytic process using pure gold for the cathode (or titanium as a starter cathode) and chloroauric acid (gold chloride-hydrochloric acid) as the electrolyte; this is made by dissolving gold with chlorine gas in the presence of ...
The video describes the electrolytic process as it is occurring on Captain Kidd's Cannon, which is on display and currently undergoing the electrolytic process. An electrolytic process is the use of electrolysis industrially to refine metals or compounds at a high purity and low cost. Some examples are the Hall-Héroult process [1] used for ...
In chemistry and manufacturing, electrolysis is a technique that uses direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction.Electrolysis is commercially important as a stage in the separation of elements from naturally occurring sources such as ores using an electrolytic cell.
Electrowinning is the oldest industrial electrolytic process. The English chemist Humphry Davy obtained sodium metal in elemental form for the first time in 1807 by the electrolysis of molten sodium hydroxide. Electrorefining of copper was first demonstrated experimentally by Maximilian, Duke of Leuchtenberg in 1847. [2]
The chloride process became obsolete with the development of the cyanide process. [22] [23] In 1887, John Stewart MacArthur, working in collaboration with brothers Dr Robert and Dr William Forrest for the Tennant Company in Glasgow, Scotland, developed the MacArthur-Forrest Process for the extraction of gold ores. By suspending the crushed ore ...
This process is limited to very thin coatings, since the reaction stops after the substrate has been completely covered. Nevertheless, it has some important applications, such as the electroless nickel immersion gold (ENIG) process used to obtain gold-plated electrical contacts on printed circuit boards.
The resulting gold is 99.5% pure, but of lower purity than gold produced by the other common refining method, the Wohlwill process, which produces gold of up to 99.999% purity. [1] [2] The Wohlwill process is commonly used for producing high-purity gold, such as in electronics work, where exacting standards of purity are required.