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Barium carbonate is the inorganic compound with the formula BaCO 3. Like most alkaline earth metal carbonates, it is a white salt that is poorly soluble in water. It occurs as the mineral known as witherite. In a commercial sense, it is one of the most important barium compounds. [5]
Barium azide – Ba(N 3) 2 [84] Barium bromide – BaBr 2; Barium carbonate – BaCO 3 [85] Barium chlorate – Ba(ClO 3) 2 [86] Barium chloride – BaCl 2 [87] Barium chromate – BaCrO 4 [88] Barium ferrate – BaFeO 4; Barium ferrite – BaFe 12 O 19 [89] Barium fluoride – BaF 2 [90] Barium hydroxide – Ba(OH) 2 [91] [92] Barium iodide ...
Barium chloride is extracted out from the mixture with water. From water solutions of barium chloride, its dihydrate (BaCl 2 ·2H 2 O) can be crystallized as colorless crystals. [2] Barium chloride can in principle be prepared by the reaction between barium hydroxide or barium carbonate with hydrogen chloride.
Barium, typically as barium nitrate imparts a yellow or "apple" green color to fireworks; [30] for brilliant green barium chloride is used. Barium peroxide is a catalyst in the aluminothermic reaction for welding rail tracks. It is also a green flare in tracer ammunition and a bleaching agent. [31]
Barium hydroxide is used in analytical chemistry for the titration of weak acids, particularly organic acids. Its aqueous solution, if clear, is guaranteed to be free of carbonate, unlike those of sodium hydroxide and potassium hydroxide, as barium carbonate is insoluble in water.
The compound hydrogen chloride has the chemical formula HCl and as such is a hydrogen halide. At room temperature, it is a colorless gas, which forms white fumes of hydrochloric acid upon contact with atmospheric water vapor. Hydrogen chloride gas and hydrochloric acid are important in technology and industry.
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).
Each axial perchlorate oxygen is hydrogen bonded to three water molecules and each trigonal oxygen is hydrogen bonded to two water molecules. This interaction is the reason that the perchlorate fails to be tetrahedral. Gallucci and Gerkin surmised that the water molecule H atoms lie in the plane at z = 1 ⁄ 4 and 3 ⁄ 4. [2]