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Inverse spinel structures have a different cation distribution in that all of the A cations and half of the B cations occupy octahedral sites, while the other half of the B cations occupy tetrahedral sites. An example of an inverse spinel is Fe 3 O 4, if the Fe 2+ (A 2+) ions are d 6 high-spin and the Fe 3+ (B 3+) ions are d 5 high-spin.
Hercynite is a spinel of regular symmetry and normal cation distribution, but some disorder occurs in its structure. It consists of ferrous (Fe 2+) ions and aluminium ions (Al 3+); however some ferric ions (Fe 3+) may be located in the structure of hercynite. [5] Melting point of this mineral is inbetween 1,692–1,767 °C (3,078–3,213 °F). [6]
Filipstadite is a very rare mineral [4] of the spinel group, with the formula (Mn,Mg)(Sb 5+ 0.5 Fe 3 + 0.5)O 4. [5] It is isometric, [3] although it was previously thought to be orthorhombic. When compared to a typical spinel, both the octahedral and tetrahedral sites are split due to cation ordering. [3] Filipstadite is chemically close to ...
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Nickel manganese oxides, [1] or nickel manganates, are spinel structure compounds of Nickel, Manganese and Oxygen of the form: Ni (x) Mn (3-x) O (y) [2] [3] Some common forms are Ni 2 MnO 4, NiMn 2 O 4, and Ni 1.5 Mn 1.5 O 4. They are most commonly formulated for use in thin film resistors and thermistors. [4]
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The mineral ceylonite has the chemical composition of (Mg, Fe 2+) Al 2 O 4, putting it into a group of minerals known as the spinel group, or the oxide spinels. The oxide spinels have a formula of the model [A][B] 2 O 4; where [A] is commonly Fe 2+, Mg 2+, or Mn 2+, and [B] is Fe 3+, Al 3+, or Cr 3+. It is an iron-rich variety of the spinel ...
2, where A is a trivalent cation such as Fe 3+ or Al 3+, B is a divalent cation such as Fe 2+, Ca 2+, or Mg 2+, and C is an alkali metal cation such as Li +, Na +, or K +. In all these minerals, the anions consist mainly of groups of four SiO 4 tetrahedra connected by shared oxygen corners so as to form