Search results
Results from the WOW.Com Content Network
A cyclopropyl group is a chemical structure derived from cyclopropane; it is typically produced in a cyclopropanation reaction. The group has an empirical formula of C 3 H 5 and chemical bonds from each of the three carbons to both of the other two.
Alkyl groups that contain one ring have the formula −C n H 2n−1, e.g. cyclopropyl and cyclohexyl. The formula of alkyl radicals are the same as alkyl groups, except the free valence "−" is replaced by the dot "•" and adding "radical" to the name of the alkyl group (e.g. methyl radical •CH 3).
From left to right: the two isomeric groups propyl and 1-methylethyl (iPr or isopropyl), and the non-isomeric cyclopropyl group. In organic chemistry, a propyl group is a three-carbon alkyl substituent with chemical formula −CH 2 CH 2 CH 3 for the linear form.
Alkyl cycloalkanes are chemical compounds with an alkyl group with a single ring of carbons to which hydrogens are attached according to the formula C n H 2n . They are named analogously to their normal alkane counterpart of the same carbon count: methylcyclopropane , methylcyclobutane , methylcyclopentane , methylcyclohexane , etc. [ 1 ]
Most cyclopropanes are not prepared from the parent cyclopropane, which is somewhat inert. Cyclopropyl groups are often prepared by cyclization of 1,3-difunctional alkanes. An example of the former, cyclopropyl cyanide is prepared by the reaction of 4-chlorobutyronitrile with a strong base. [1]
In the 1960s, shortly after the rearrangement was discovered, it was established that the activation energy for the vinylcyclopropane rearrangement is around 50 kcal/mol. [21] The kinetic data obtained for this rearrangement were consistent with a concerted mechanism where cleavage of the cyclopropyl carbon-carbon bond was rate-limiting.
An exocyclic group is always shown outside the ring structure, take for instance the exocyclic double bond of the former molecule. Isotoluenes are a prominent class of compounds with exocyclic double bonds. The placement of double bonds in many alicyclic compounds can be predicted with Bredt's rule.
Cyclopropanol is an organic compound with the chemical formula C 3 H 6 O. It contains a cyclopropyl group with a hydroxyl group attached to it. The compound is highly unstable due to the three-membered ring, and is susceptible to reactions that open the ring.