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In thermodynamics, the enthalpy of sublimation, or heat of sublimation, is the heat required to sublimate (change from solid to gas) one mole of a substance at a given combination of temperature and pressure, usually standard temperature and pressure (STP). It is equal to the cohesive energy of the solid.
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
Common transfer types are Heat Transfer Vinyl cut with a vinyl cutter, Printable Heat Transfer Vinyl, Inkjet Transfer Paper, Laser Transfer Paper, Plastisol Transfers, and Sublimation. Using a Heat Press to apply a heat transfer is a way to ensure accurate time, temperature, and pressure, which are all essential to the transfer process. [1]
J.A. Dean (ed), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
In order to transfer the image from the paper to the substrate, it requires a heat press process that is a combination of time, temperature and pressure. The heat press applies this special combination, which can change depending on the substrate, to “transfer” the sublimation dyes at the molecular level into the substrate.
The most common dyes used for sublimation activate at 350 degrees Fahrenheit / 175 degrees Celsius. However, a range of 380 to 420 degrees Fahrenheit / 195 to 215 degrees Celsius is normally recommended for optimal color. The result of the sublimation transfer process is a nearly permanent, high-resolution, full-color print.
Sensible heat is sensed or felt in a process as a change in the body's temperature. Latent heat is energy transferred in a process without change of the body's temperature, for example, in a phase change (solid/liquid/gas). Both sensible and latent heats are observed in many processes of transfer of energy in nature.
The form of the cooled surface often is a so-called cold finger which for very low-temperature sublimation may actually be cryogenically cooled. If the operation is a batch process , then the sublimed material can be collected from the cooled surface once heating ceases and the vacuum is released.
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