Search results
Results from the WOW.Com Content Network
In thermodynamics, an isobaric process is a type of thermodynamic process in which the pressure of the system stays constant: ΔP = 0. The heat transferred to the system does work, but also changes the internal energy (U) of the system. This article uses the physics sign convention for work, where positive work is work done by the system.
Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, [1] or cause changes in electromagnetic, [2] [3] [4] or gravitational [5] variables.
The process does no pressure-volume work, since such work is defined by =, where P is pressure. The sign convention is such that positive work is performed by the system on the environment. If the process is not quasi-static, the work can perhaps be done in a volume constant thermodynamic process. [1]
A Carnot cycle is an ideal thermodynamic cycle proposed by French physicist Sadi Carnot in 1824 and expanded upon by others in the 1830s and 1840s. By Carnot's theorem, it provides an upper limit on the efficiency of any classical thermodynamic engine during the conversion of heat into work, or conversely, the efficiency of a refrigeration system in creating a temperature difference through ...
In solution chemistry and biochemistry, the Gibbs free energy decrease (∂G/∂ξ, in molar units, denoted cryptically by ΔG) is commonly used as a surrogate for (−T times) the global entropy produced by spontaneous chemical reactions in situations where no work is being done; or at least no "useful" work; i.e., other than perhaps ± P dV.
In the process of passing through a cycle, the working fluid (system) may convert heat from a warm source into useful work, and dispose of the remaining heat to a cold sink, thereby acting as a heat engine. Conversely, the cycle may be reversed and use work to move heat from a cold source and transfer it to a warm sink thereby acting as a heat ...
An example of a cycle of idealized thermodynamic processes which make up the Stirling cycle. A quasi-static thermodynamic process can be visualized by graphically plotting the path of idealized changes to the system's state variables. In the example, a cycle consisting of four quasi-static processes is shown.
Rigid boundary – not allowing exchange of work: A mechanically isolated system; One example is fluid being compressed by a piston in a cylinder. Another example of a closed system is a bomb calorimeter, a type of constant-volume calorimeter used in measuring the heat of combustion of a particular reaction. Electrical energy travels across the ...