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Thermodynamic work is one of the principal kinds of process by which a thermodynamic system can interact with and transfer energy to its surroundings. This results in externally measurable macroscopic forces on the system's surroundings, which can cause mechanical work, to lift a weight, for example, [1] or cause changes in electromagnetic, [2] [3] [4] or gravitational [5] variables.
In thermodynamics, an isobaric process is a type of thermodynamic process in which the pressure of the system stays constant: ΔP = 0. The heat transferred to the system does work, but also changes the internal energy (U) of the system. This article uses the physics sign convention for work, where positive work is work done by the system.
The process does no pressure-volume work, since such work is defined by =, where P is pressure. The sign convention is such that positive work is performed by the system on the environment. If the process is not quasi-static, the work can perhaps be done in a volume constant thermodynamic process. [1]
In solution chemistry and biochemistry, the Gibbs free energy decrease (∂G/∂ξ, in molar units, denoted cryptically by ΔG) is commonly used as a surrogate for (−T times) the global entropy produced by spontaneous chemical reactions in situations where no work is being done; or at least no "useful" work; i.e., other than perhaps ± P dV.
For example, the first law allows the process of a cup falling off a table and breaking on the floor, as well as allowing the reverse process of the cup fragments coming back together and 'jumping' back onto the table, while the second law allows the former and denies the latter.
The actual vapor power cycle differs from the ideal Rankine cycle because of irreversibilities in the inherent components caused by fluid friction and heat loss to the surroundings; fluid friction causes pressure drops in the boiler, the condenser, and the piping between the components, and as a result the steam leaves the boiler at a lower ...
A process during which the entropy remains constant is called an isentropic process, written = or =. [12] Some examples of theoretically isentropic thermodynamic devices are pumps, gas compressors, turbines, nozzles, and diffusers.
In lean thinking, inappropriate processing or excessive processing of goods or work in process, "doing more than is necessary", is seen as one of the seven wastes (Japanese term: muda) which do not add value to a product. [9] [10]