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Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
The most reactive metals, such as sodium, will react with cold water to produce hydrogen and the metal hydroxide: 2 Na (s) + 2 H 2 O (l) →2 NaOH (aq) + H 2 (g) Metals in the middle of the reactivity series, such as iron , will react with acids such as sulfuric acid (but not water at normal temperatures) to give hydrogen and a metal salt ...
When an alkali metal is dropped into water, it produces an explosion, of which there are two separate stages. The metal reacts with the water first, breaking the hydrogen bonds in the water and producing hydrogen gas; this takes place faster for the more reactive heavier alkali metals. Second, the heat generated by the first part of the ...
Addition of a small amount of caesium to cold water is explosive. Caesium metal is highly reactive and pyrophoric. It ignites spontaneously in air, and reacts explosively with water even at low temperatures, more so than the other alkali metals. [14] It reacts with ice at temperatures as low as −116 °C (−177 °F). [17]
Metallic sodium is generally less reactive than potassium and more reactive than lithium. [20] Sodium metal is highly reducing, with the standard reduction potential for the Na + /Na couple being −2.71 volts, [21] though potassium and lithium have even more negative potentials. [22]
A metal ion in aqueous solution or aqua ion is a cation, dissolved in water, of chemical formula [M(H 2 O) n] z+.The solvation number, n, determined by a variety of experimental methods is 4 for Li + and Be 2+ and 6 for most elements in periods 3 and 4 of the periodic table.
The eutectic mixture consists of 77% potassium and 23% sodium by mass (NaK-77), and it is a liquid from −12.6 to 785 °C (9.3 to 1,445.0 °F), and has a density of 0.866 g/cm 3 at 21 °C (70 °F) and 0.855 g/cm 3 at 100 °C (212 °F), making it less dense than water. [3] It is highly reactive with water and is stored usually under hexane or ...
Hydroxyl radicals are highly reactive and consequently short-lived; however, they form an important part of radical chemistry. Most notably hydroxyl radicals are produced from the decomposition of hydroperoxides (ROOH) or, in atmospheric chemistry, by the reaction of excited atomic oxygen with water.