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The first law of thermodynamics is a formulation of the law of conservation of energy in the context of thermodynamic processes. The law distinguishes two principal forms of energy transfer, heat and thermodynamic work , that modify a thermodynamic system containing a constant amount of matter.
The first law of thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic processes. In general, the conservation law states that the total energy of an isolated system is constant; energy can be transformed from one form to another, but can be neither created nor destroyed.
The zeroth law is of importance in thermometry, because it implies the existence of temperature scales. In practice, C is a thermometer, and the zeroth law says that systems that are in thermodynamic equilibrium with each other have the same temperature. The law was actually the last of the laws to be formulated. First law of thermodynamics
[1] [2] As a key concept in thermodynamics, the adiabatic process supports the theory that explains the first law of thermodynamics. The opposite term to "adiabatic" is diabatic. Some chemical and physical processes occur too rapidly for energy to enter or leave the system as heat, allowing a convenient "adiabatic approximation". [3]
From the first law of thermodynamics, the energy output cannot exceed the input, and by the second law of thermodynamics it cannot be equal in a non-ideal process, so < When expressed as a percentage, the thermal efficiency must be between 0% and 100%.
Note that the state equation, given by the first law of thermodynamics (i.e. conservation of energy), is written in the following form (assuming no mass transfer or radiation). This form is more general and particularly useful to recognize which property (e.g. c p or ρ {\displaystyle \rho } ) influences which term.
Researchers have made a breakthrough in applying the first law of thermodynamics to complex systems, rewriting the way we understand complex energetic systems.
In thermodynamics, the Gibbs free energy (or Gibbs energy as the recommended name; symbol ) is a thermodynamic potential that can be used to calculate the maximum amount of work, other than pressure–volume work, that may be performed by a thermodynamically closed system at constant temperature and pressure.