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1,4-Dichlorobenzene (1,4-DCB, p-DCB, or para-dichlorobenzene, sometimes abbreviated as PDCB or para) is an aryl chloride and isomer of dichlorobenzene with the formula C 6 H 4 Cl 2. This colorless solid has a strong odor. The molecule consists of a benzene ring with two chlorine atoms (replacing hydrogen atoms) on opposing sites of the ring.
1,2-Dichlorobenzene or ortho-dichlorobenzene; 1,3-Dichlorobenzene or meta-dichlorobenzene; 1,4-Dichlorobenzene or para-dichlorobenzene. All three isomers are colorless chlorobenzenes with the formula C 6 H 4 Cl 2. They differ structurally based on where the two chlorine atoms are attached to the ring.
1,4-Dichlorobenzene; Dichlorofulvenes; 1,6-Dichloro-2,4-hexadiyne This page was last edited on 28 August 2022, at 12:56 (UTC). Text is available under the Creative ...
The bacterium Rhodococcus phenolicus degrades chlorobenzene, dichlorobenzene and phenol as sole carbon sources. [ 12 ] Upon entering the body, typically via contaminated air, chlorobenzene is excreted both via the lungs and the urinary system.
The 1,3- isomer is uncommon because it is a meta- compound, while chlorine, like all halogens, is an ortho/para-director in terms of electrophilic aromatic substitution. It is mainly used as a precursor to 1,2-dichloro-4-nitrobenzene, an intermediate in the synthesis of agrochemicals. [5] In terms of niche applications, 1,2-dichlorobenzene is a ...
C 6 H 6 + C 2 H 4 → C 6 H 5 C 2 H 5. The diethylbenzene is an inadvertent side product. C 6 H 5 C 2 H 5 + C 2 H 4 → C 6 H 4 (C 2 H 5) 2. Using shape-selective zeolite catalysts, the para isomer can be produced in high selectivity. Much diethylbenzene is recycled by transalkylation to give ethylbenzene: [1] C 6 H 4 (C 2 H 5) 2 + C 6 H 6 → ...
The LD50 (oral, rats) is 756 mg/kg. Animal studies have shown that 1,2,4-trichlorobenzene affects the liver and kidney, and is possibly a teratogen. [4] There is no regulated occupational exposure limit for chemical exposure, but the National Institute for Occupational Safety and Health recommends no greater exposure than 5 ppm, over an 8-hour workday.
Thus, the four remaining hydrogens in meta-dichlorobenzene still fall into three classes, while those of ortho- fall into two, and those of para- are all equivalent again. Still, some of these 3 + 2 + 1 = 6 substitutions end up yielding the same structure, so there are only three structurally distinct trichlorobenzenes: 1,2,3-, 1,2,4-, and 1,3,5-.