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The second law of thermodynamics is a physical law based on universal empirical observation concerning heat and energy interconversions.A simple statement of the law is that heat always flows spontaneously from hotter to colder regions of matter (or 'downhill' in terms of the temperature gradient).
A prime example of this irreversibility is the transfer of heat by conduction or radiation. It was known long before the discovery of the notion of entropy that when two bodies, initially of different temperatures, come into direct thermal connection, then heat immediately and spontaneously flows from the hotter body to the colder one.
Such spontaneous heat transfer always occurs from a region of high temperature to another region of lower temperature, as described in the second law of thermodynamics. Heat convection occurs when the bulk flow of a fluid (gas or liquid) carries its heat through the fluid. All convective processes also move heat partly by diffusion, as well.
A traditional version of the second law of thermodynamics states: Heat does not spontaneously flow from a colder body to a hotter body. The second law refers to a system of matter and radiation, initially with inhomogeneities in temperature, pressure, chemical potential, and other intensive properties , that are due to internal 'constraints ...
The second law of thermodynamics states that when an isolated body of material starts from an equilibrium state, in which portions of it are held at different states by more or less permeable or impermeable partitions, and a thermodynamic operation removes or makes the partitions more permeable, then it spontaneously reaches its own new state ...
The macroscopic energy equation for infinitesimal volume used in heat transfer analysis is [6] = +, ˙, where q is heat flux vector, −ρc p (∂T/∂t) is temporal change of internal energy (ρ is density, c p is specific heat capacity at constant pressure, T is temperature and t is time), and ˙ is the energy conversion to and from thermal ...
The second law can be phrased in several different ways, the most intuitive of which is that heat flows spontaneously from hotter to colder places; relevant here is that the law observes that in every macroscopic process, there is friction or something close to it; another statement is that no heat engine (an engine which produces work while ...
The molar heat capacity is the heat capacity per unit amount (SI unit: mole) of a pure substance, and the specific heat capacity, often called simply specific heat, is the heat capacity per unit mass of a material. Heat capacity is a physical property of a substance, which means that it depends on the state and properties of the substance under ...