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Organic azides also provide an example of an insertion reaction in organic synthesis and, like the above examples, the transformations proceed with loss of nitrogen gas. When tosyl azide reacts with norbornadiene, a ring expansion reaction takes place in which a nitrogen atom is inserted into a carbon-carbon bond α- to the bridge head: [14]
In telecommunications, insertion loss is the loss of signal power resulting from the insertion of a device in a transmission line or optical fiber and is usually expressed in decibels (dB). If the power transmitted to the load before insertion is P T and the power received by the load after insertion is P R, then the insertion loss in decibels ...
N.B. Pilling and R.E. Bedworth [2] suggested in 1923 that metals can be classed into two categories: those that form protective oxides, and those that cannot. They ascribed the protectiveness of the oxide to the volume the oxide takes in comparison to the volume of the metal used to produce this oxide in a corrosion process in dry air.
In organic chemistry, a cross-coupling reaction is a reaction where two different fragments are joined. Cross-couplings are a subset of the more general coupling reactions. Often cross-coupling reactions require metal catalysts. One important reaction type is this:
Conversion and its related terms yield and selectivity are important terms in chemical reaction engineering.They are described as ratios of how much of a reactant has reacted (X — conversion, normally between zero and one), how much of a desired product was formed (Y — yield, normally also between zero and one) and how much desired product was formed in ratio to the undesired product(s) (S ...
In organometallic chemistry, a migratory insertion is a type of reaction wherein two ligands on a metal complex combine. It is a subset of reactions that very closely resembles the insertion reactions , and both are differentiated by the mechanism that leads to the resulting stereochemistry of the products.
In particular, the sheets of carbon that comprise graphite can be pried apart by the insertion (intercalation) of ions. The graphite is viewed as a host and the inserted ions as guests. The materials have the formula (guest)C n where n ≥ 6. The insertion of the guests increases the distance between the carbon sheets.
The Widom insertion method is a statistical thermodynamic approach to the calculation of material and mixture properties. It is named for Benjamin Widom , who derived it in 1963. [ 1 ] In general, there are two theoretical approaches to determining the statistical mechanical properties of materials.