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Surface tension is an important factor in the phenomenon of capillarity. Surface tension has the dimension of force per unit length, or of energy per unit area. [4] The two are equivalent, but when referring to energy per unit of area, it is common to use the term surface energy, which is a more general term in the sense that it applies also to ...
In surface science, a tensiometer is a measuring instrument used to measure the surface tension (γ) of liquids or surfaces.Tensiometers are used in research and development laboratories to determine the surface tension of liquids like coatings, lacquers or adhesives.
In the equation, m 1 and σ 1 represent the mass and surface tension of the reference fluid and m 2 and σ 2 the mass and surface tension of the fluid of interest. If we take water as a reference fluid, = If the surface tension of water is known which is 72 dyne/cm, we can calculate the surface tension of the specific fluid from the equation.
The measurement is performed with a force tensiometer, which typically uses an electrobalance to measure the excess force caused by the liquid being pulled up and automatically calculates and displays the surface tension corresponding to the force. Earlier, torsion wire balances were commonly used.
(σ: surface tension, ΔP max: maximum pressure drop, R cap: radius of capillary) Later, after the maximum pressure, the pressure of the bubble decreases and the radius of the bubble increases until the bubble is detached from the end of a capillary and a new cycle begins. This is not relevant to determine the surface tension. [3]
The magnitude of the capillary force on the plate is proportional to the wetted perimeter, = +, and to the surface tension of the liquid-air interface. A Wilhelmy plate is a thin plate that is used to measure equilibrium surface or interfacial tension at an air–liquid or liquid–liquid interface.
This method is especially used to compare and measure the critical surface tension of low-energy solids (mainly plastics) very quickly and easily. Figure 4 in ZIsman's published article from 1964 [1] shows the critical surface tension as a measure of wettability of Polyethylene. Zisman published this analysis in 1964 and used a variety of ...
An approximate theory was developed by Bernard Vonnegut [3] in 1942 to measure the surface tension of the fluids, which is based on the principle that the interfacial tension and centrifugal forces are balanced at mechanical equilibrium. This theory assumes that the droplet's length L is much greater than its radius R, so that it may be ...
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