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A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
The "chart" actually consists of a pair of charts: One to monitor the process standard deviation (as approximated by the sample moving range) and another to monitor the process mean, as is done with the ¯ and s and individuals control charts.
The figure below illustrates the relationship between the blank, the limit of detection (LOD), and the limit of quantitation (LOQ) by showing the probability density function for normally distributed measurements at the blank, at the LOD defined as 3 × standard deviation of the blank, and at the LOQ defined as 10 × standard deviation of the ...
The binomial distribution is the basis for the p-chart and requires the following assumptions: [2]: 267 The probability of nonconformity p is the same for each unit; Each unit is independent of its predecessors or successors; The inspection procedure is the same for each sample and is carried out consistently from sample to sample
The "chart" actually consists of a pair of charts: One to monitor the process standard deviation and another to monitor the process mean, as is done with the ¯ and R and individuals control charts.
The X-bar chart is always used in conjunction with a variation chart such as the ¯ and R chart or ¯ and s chart. The R-chart shows sample ranges (difference between the largest and the smallest values in the sample), while the s-chart shows the samples' standard deviation. The R-chart was preferred in times when calculations were performed ...
The above eight rules apply to a chart of a variable value. A second chart, the moving range chart, can also be used but only with rules 1, 2, 3 and 4. Such a chart plots a graph of the maximum value - minimum value of N adjacent points against the time sample of the range.
A tolerance interval (TI) is a statistical interval within which, with some confidence level, a specified sampled proportion of a population falls. "More specifically, a 100×p%/100×(1−α) tolerance interval provides limits within which at least a certain proportion (p) of the population falls with a given level of confidence (1−α)."