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A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
The figure below illustrates the relationship between the blank, the limit of detection (LOD), and the limit of quantitation (LOQ) by showing the probability density function for normally distributed measurements at the blank, at the LOD defined as 3 × standard deviation of the blank, and at the LOQ defined as 10 × standard deviation of the ...
In probability theory, a log-normal (or lognormal) distribution is a continuous probability distribution of a random variable whose logarithm is normally distributed.Thus, if the random variable X is log-normally distributed, then Y = ln(X) has a normal distribution.
In statistics, deviance is a goodness-of-fit statistic for a statistical model; it is often used for statistical hypothesis testing.It is a generalization of the idea of using the sum of squares of residuals (SSR) in ordinary least squares to cases where model-fitting is achieved by maximum likelihood.
Correction factor versus sample size n.. When the random variable is normally distributed, a minor correction exists to eliminate the bias.To derive the correction, note that for normally distributed X, Cochran's theorem implies that () / has a chi square distribution with degrees of freedom and thus its square root, / has a chi distribution with degrees of freedom.
A tolerance interval (TI) is a statistical interval within which, with some confidence level, a specified sampled proportion of a population falls. "More specifically, a 100×p%/100×(1−α) tolerance interval provides limits within which at least a certain proportion (p) of the population falls with a given level of confidence (1−α)."
The R-chart shows sample ranges (difference between the largest and the smallest values in the sample), while the s-chart shows the samples' standard deviation. The R-chart was preferred in times when calculations were performed manually, as the range is far easier to calculate than the standard deviation; with the advent of computers, ease of ...
The table shown on the right can be used in a two-sample t-test to estimate the sample sizes of an experimental group and a control group that are of equal size, that is, the total number of individuals in the trial is twice that of the number given, and the desired significance level is 0.05. [4] The parameters used are: