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This lists the character tables for the more common molecular point groups used in the study of molecular symmetry. These tables are based on the group-theoretical treatment of the symmetry operations present in common molecules, and are useful in molecular spectroscopy and quantum chemistry. Information regarding the use of the tables, as well ...
The irreducible complex characters of a finite group form a character table which encodes much useful information about the group G in a concise form. Each row is labelled by an irreducible character and the entries in the row are the values of that character on any representative of the respective conjugacy class of G (because characters are class functions).
Robert Mulliken was the first to publish character tables in English (1933), and E. Bright Wilson used them in 1934 to predict the symmetry of vibrational normal modes. [13]. For this reason, the notation used to label irreps in the above table is called Mulliken notation and for asymmetric groups it consists of letters A and B with subscripts ...
In Schoenflies notation, point groups are denoted by a letter symbol with a subscript. The symbols used in crystallography mean the following: C n (for cyclic) indicates that the group has an n-fold rotation axis.
The handbook was originally published in 1928 by the Chemical Rubber Company (now CRC Press) as a supplement (Mathematical Tables) to the CRC Handbook of Chemistry and Physics. Beginning with the 10th edition (1956), it was published as CRC Standard Mathematical Tables and kept this title up to the 29th edition (1991).
In other cases there is no point around which the point group applies. The notation is somewhat ambiguous, without a table giving more information. For example, space groups I23 and I2 1 3 (nos. 197 and 199) both contain two-fold rotational axes as well as two-fold screw axes. In the first, the two-fold axes intersect the three-fold axes ...
Let Γ be a finite subgroup of SO(3), the three-dimensional rotation group.There is a natural homomorphism f of SU(2) onto SO(3) which has kernel {±I}. [4] This double cover can be realised using the adjoint action of SU(2) on the Lie algebra of traceless 2-by-2 skew-adjoint matrices or using the action by conjugation of unit quaternions.
The space of complex-valued class functions of a finite group G has a natural inner product: , := | | () ¯ where () ¯ denotes the complex conjugate of the value of on g.With respect to this inner product, the irreducible characters form an orthonormal basis for the space of class functions, and this yields the orthogonality relation for the rows of the character table: