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Dimethyldichlorosilane is a tetrahedral organosilicon compound with the formula Si(CH 3) 2 Cl 2. At room temperature it is a colorless liquid that readily reacts with water to form both linear and cyclic Si-O chains. Dimethyldichlorosilane is made on an industrial scale as the principal precursor to dimethylsilicone and polysilane compounds.
Several crystal structures containing PdCl 2 (PPh 3) 2 have been reported. In all of the structures, PdCl 2 (PPh 3) 2 adopts a square planar coordination geometry and the trans isomeric form. [5] [6] [7] [8]
2 ((CH 3) 3 SiCl + H 2 O → [(CH 3) 3 Si] 2 O + 2 HCl. The analogous reaction of dimethyldichlorosilane gives siloxane polymers or rings: n (CH 3) 2 SiCl 2 + n H 2 O → [(CH 3) 2 SiO] n + 2n HCl. Many compounds containing Si-Cl bonds can be converted to hydrides using lithium aluminium hydride, This kind of conversion was demonstrated for the ...
Dichlorosilane, or DCS as it is commonly known, is a chemical compound with the formula H 2 SiCl 2. In its major use, it is mixed with ammonia (NH 3) in LPCVD chambers to grow silicon nitride in semiconductor processing. A higher concentration of DCS·NH 3 (i.e. 16:1), usually results in lower stress nitride films.
Dichlorobis(triphenylphosphine)nickel(II) refers to a pair of metal phosphine complexes with the formula NiCl 2 [P(C 6 H 5) 3] 2. The compound exists as two isomers, a paramagnetic dark blue solid and a diamagnetic red solid. These complexes function as catalysts for organic synthesis. [1]
Most polysiloxanes feature organic substituents, e.g., [(CH 3) 2 SiO] n and [(C 6 H 5) 2 SiO)] n. All polymerized siloxanes or polysiloxanes, silicones consist of an inorganic silicon–oxygen backbone chain (···−Si−O−Si−O−Si−O−···) with two groups attached to each silicon center. The materials can be cyclic or polymeric.
Silanes with one, two, three, or four Si-H bonds are called hydrosilanes. Silane is again the parent member. Examples: triethylsilane (HSi(C 2 H 5) 3) and triethoxysilane (HSi(OC 2 H 5) 3). Polysilanes are organosilicon compounds with the formula (R 2 Si) n. They feature Si-Si bonds. Attracting more interest are the organic derivatives such as ...
MeSiCl 3 + 3 H 2 O → MeSi(OH) 3 + 3 HCl. The silanol is unstable and will eventually condense to give a polymer network: MeSi(OH) 3 → MeSiO 1.5 + 1.5 H 2 O. Methyltrichlorosilane undergoes alcoholysis (reaction with alcohol) to give alkoxysilanes. Methanol converts it to trimethoxymethylsilane: MeSiCl 3 + 3 CH 3 OH → MeSi(OCH 3) 3 + 3 HCl