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The exact relationship depends on the nature of the reactions at the two electrodes. For the electrolysis of aqueous copper(II) sulfate (CuSO 4) as an example, with Cu 2+ (aq) and SO 2− 4 (aq) ions, the cathode reaction is the reduction Cu 2+ (aq) + 2 e − → Cu(s) and the anode reaction is the corresponding oxidation of Cu to Cu 2+.
It is commonly abbreviated as LiHMDS or Li(HMDS) (lithium hexamethyldisilazide - a reference to its conjugate acid HMDS) and is primarily used as a strong non-nucleophilic base and as a ligand. Like many lithium reagents, it has a tendency to aggregate and will form a cyclic trimer in the absence of coordinating species.
Phenyllithium was first produced by the reaction of lithium metal with diphenylmercury: [5] (C 6 Η 5) 2 Ηg + 2Li → 2C 6 Η 5 Li + Ηg. Reaction of a phenyl halide with lithium metal produces phenyllithium: X-Ph + 2Li → Ph-Li + LiX. Phenyllithium can also be synthesized with a metal-halogen exchange reaction: n-BuLi + X-Ph → n-BuX + Ph-Li
In chemistry, an acid–base reaction is a chemical reaction that occurs between an acid and a base.It can be used to determine pH via titration.Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their application in solving related problems; these are called the acid–base theories, for example, Brønsted–Lowry acid–base theory.
It is a common practice to determine equilibrium constants in solutions containing an electrolyte at high ionic strength such that the activity coefficients are effectively constant. However, when the ionic strength is changed the measured equilibrium constant will also change, so there is a need to estimate individual (single ion) activity ...
An acid–base titration is a method of quantitative analysis for determining the concentration of Brønsted-Lowry acid or base (titrate) by neutralizing it using a solution of known concentration (titrant). [1] A pH indicator is used to monitor the progress of the acid–base reaction and a titration curve can be constructed. [1]
The E and C parameters refer, respectively, to the electrostatic and covalent contributions to the strength of the bonds that the acid and base will form. The equation is -ΔH = E A E B + C A C B + W. The W term represents a constant energy contribution for acid–base reaction such as the cleavage of a dimeric acid or base.
A simple buffer solution consists of a solution of an acid and a salt of the conjugate base of the acid. For example, the acid may be acetic acid and the salt may be sodium acetate . The Henderson–Hasselbalch equation relates the pH of a solution containing a mixture of the two components to the acid dissociation constant , K a of the acid ...