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In some contexts, water of crystallization is the total mass of water in a substance at a given temperature and is mostly present in a definite (stoichiometric) ratio. Classically, "water of crystallization" refers to water that is found in the crystalline framework of a metal complex or a salt, which is not directly bonded to the metal cation.
One example is the pair [CrCl(H 2 O) 5]Cl 2 •H 2 O and [Cr(H 2 O) 6]Cl 3. [1] The former has one water of crystallization but the latter does not. Another example is the pair of titanium(III) chlorides, [Ti(H 2 O) 6]Cl 3 and [Ti(H 2 O) 4 Cl 2]Cl(H 2 O) 2. The former is violet and the latter, with two molecules of water of crystallization, is ...
Another example is chloral hydrate, CCl 3 −CH(OH) 2, which can be formed by reaction of water with chloral, CCl 3 −CH=O. Many organic molecules, as well as inorganic molecules, form crystals that incorporate water into the crystalline structure without chemical alteration of the organic molecule ( water of crystallization ).
An example of this crystallization process is the production of Glauber's salt, a crystalline form of sodium sulfate. In the diagram, where equilibrium temperature is on the x-axis and equilibrium concentration (as mass percent of solute in saturated solution) in y-axis , it is clear that sulfate solubility quickly decreases below 32.5 °C.
Some mineral structures, for example, montmorillonite, are capable of including a variable amount of water without significant change to the mineral structure. [citation needed] Hydration is the mechanism by which hydraulic binders such as Portland cement develop strength. A hydraulic binder is a material that can set and harden submerged in ...
i.e., crystallization takes a time that decreases as one over the one-quarter power of the nucleation rate per unit volume, ˙, and one over the three-quarters power of the growth velocity ˙. Typical crystallites grow for some fraction of the crystallization time t X {\displaystyle t_{X}} and so have a linear dimension G ˙ t X {\displaystyle ...
If you've been having trouble with any of the connections or words in Friday's puzzle, you're not alone and these hints should definitely help you out. Plus, I'll reveal the answers further down ...
"Nickel dichloride hexahydrate" consists of the chloride complex trans-[NiCl 2 (H 2 O) 4 plus water of crystallization. As indicated in the table below, many hydrates of metal chlorides are molecular complexes. [78] [79] These compounds are often important commercial sources of transition metal chlorides. Several hydrated metal chlorides are ...